The Mixed distribution model of time headway plays an important role in Intelligent Transportation System. A more accurate improved model based on a new traffic state classification method and correlation coefficient method was established in this study. Upon analyzing traffic data from three unban roads in Nanjing, China from December 8, 2017 to April 24, 2018 in clear days free of fogs and haze, it was found that 1) the improved model dwarfs the other models, for it boasts higher goodness-of-fit and it represents the only one to successfully pass the Chi-square test. 2) the improved model shows better performance in application because the relative errors between the field traffic rate and calculated traffic rate obtained from the improved model are the smallest. 3) the goodness-of-fit of the improved model is affected by traffic state, and the fitting precision of the improved model under four states is the best. Thus, it is hard to tell performance of which model established under two states or three-state model is better. 4) correlation coefficients between time headway and the absolute value of relative speed make the improved Mixed model more fitted and precise. The improved model proposed in this study is a more accurate time headway distribution model.