Coin-like α-Fe₂O₃@CoFe₂O₄ Core–Shell Composites with Excellent Electromagnetic Absorption Performance

Abstract

In this paper, we designed a novel core-shell composite for microwave absorption application in which the α-Fe2O3 and the porous CoFe2O4 nanospheres served as the core and shell, respectively. Interestingly, during the solvothermal process, the solvent ratio (V) of PEG-200 to distilled water played a key role in the morphology of α-Fe2O3 for which irregular flake, coin-like, and thinner coin-like forms of α-Fe2O3 can be produced with the ratios of 1:7, 1:3, and 1:1, respectively. The porous 70 nm diameter CoFe2O4 nanospheres were generated as the shell of α-Fe2O3. It should be noted that the CoFe2O4 coating layer did not damage the original shape of α-Fe2O3. As compared with the uncoated α-Fe2O3, the Fe2O3@CoFe2O4 composites exhibited improved microwave absorption performance over the tested frequency range (2-18 GHz). In particular, the optimal reflection loss value of the flake-like composite can reach -60 dB at 16.5 GHz with a thin coating thickness of 2 mm. Furthermore, the frequency bandwidth corresponding to the RLmin value below -10 dB was up to 5 GHz (13-18 GHz). The enhanced microwave absorption properties of these composites may originate from the strong electron polarization effect (i.e., the electron polarization between Fe and Co) and the electromagnetic wave scattering on this special porous core-shell structure. In addition, the synergy effect between α-Fe2O3 and CoFe2O4 also favored balancing the electromagnetic parameters. Our results provided a promising approach for preparing an absorbent with good absorption intensity and a broad frequency that was lightweight.

High-performance microwave absorption of flexible nanocomposites based on flower-like Co superstructures and polyvinylidene fluoride

“…10 Many researchers have investigated the wave absorption properties of ferromagnetic metal particles, such as Fe 3 O 4 , 11 FeCo, 12 Ni/ Co, 10 MnFe 2 O 4 , 13 a-Fe 2 O 3 @CoFe 2 O 4 (ref. 14) and so on. In addition, to achieve better absorbing performance, the composites of ferromagnetic metallic microparticles dispersing into insulating matrix have been widely studied.…”

Controllable and Large-Scale Synthesis of Carbon Nanostructures: A Review on Bamboo-Like Nanotubes

“…Also, we have shown that HRTEM can further provide information about particle size distribution and lattice fringe of the carbon nanotubes and related catalysts [77][78][79][80][81][82][83][84][85][86][87][88][89]. The controllable synthesis of carbon nanotubes with tailored properties is certainly a challenge for researchers thanks to their valuable applications in several fields.…”

Enhanced high-frequency absorption of anisotropic Fe3O4/graphene nanocomposites

“…And it is −12.0 dB at 11.3 GHz with the thickness of 1.5 mm for another conductive PPy/MnFe 2 O 4 nanocomposite scattering in resin acrylic10. For one more example, the optimal reflection loss value of the coin-like α-Fe 2 O 3 @CoFe 2 O 4 core-shell composite can reach −60 dB at 16.5 GHz with a thickness of 2.0 mm11. As a wave absorption material, Fe 3 O 4 have been studied extensively for its excellent absorption properties by virtue of strong permeability and relative high resistivity.…”