This research demonstrates a complete solution prepared environment-friendly high-performance solid-state BiOI photovoltaic cell with high-short-circuit current for the first time. All the layers have been prepared at room temperature in the atmosphere without using the vacuum process. The photovoltaic properties are improved with employing both electron transport layer (ETL) and hole transport layer (HTL) and with increasing the cycle number of the SILAR process up to 30 cycles where the maximum short-circuit current density, J SC = 7.6 mA/cm 2 and the open-circuit voltage, V OC = 0.63 V, respectively. The ETL and HTL effects on the photovoltaic properties are discussed together with absorption spectrum and external quantum efficiency.