The piezoelectric potential output has been studied using a ZnO nanorods (NRs) grown atomic force microscope (AFM) tip in lieu of the normally used AFM tip. The ZnO NRs were synthesised on the AFM tip and on the fluorine-doped tin oxide (FTO) glass substrate using the aqueous chemical growth method. The as-grown ZnO NRs were highly dense, well aligned and uniform both on the tip and on the substrate. The structural study was performed using X-ray diffraction and scanning electron microscopy techniques. The piezoelectric properties of as-grown ZnO NRs were investigated using an AFM in contact mode. In comparison to the AFM tip without ZnO NRs, extra positive voltage peaks were observed when the AFM tip with ZnO NRs was used. The pair of ZnO NRs on the AFM tip and on the FTO glass substrate together worked as two oppositely gliding walls (composed of ZnO NRs) and showed an enhancement in the amount of the harvested energy as much as eight times. This approach demonstrates that the use of the AFM tip with ZnO NRs is not only a good alternative to improve the design of nanogenerators to obtain an enhanced amount of harvested energy but is also simple, reliable and cost-effective.1. Introduction: Owing to increasing use of energy, it is highly desirable to explore/improve different resources of energy to fill the gap between the demand for and the supply of energy. One possible approach that has the potential to fill (partially) this gap is the use of nanostructures to modify/design/develop self-powered nanodevices that can harvest their operating energy from the environment. Since all the systems that exist at present are fully dependent on a power source (normally a small-sized battery), it is extremely worthwhile to keep the size of the battery as small as possible. However, the reduced size of the battery will affect its lifetime. Therefore, the key requirement is to build such self-powered nanosystems that are not only able to scavenge their desired energy from the environment but also work independently with an uninterrupted supply of energy. Scientists and researchers have tried hard to explore different ways and means to harvest energy from the environment just by converting mechanical, vibrational or thermal energy into electricity [1]. This type of energy becomes more important when the available sources of energy are expensive or insufficient. Designing a nanogenerator (NG) in such a way that it can convert mechanical energy into electric energy by utilising the piezoelectric effect is an approach that has been developed in the recent past [2][3][4]. This kind of piezoelectric NG would not only be helpful for developing new nanodevices but can be utilised to build self-powered systems as well. This is why in recent years a lot of work has been done, first to fabricate these NGs, and then to improve their performance either by enhancing/increasing their efficiency in terms of harvested energy or by minimising the cost or by improving their reliability etc.