The deep coal mining in the North China type of coalfield is generally threatened by the underlying limestone water of Taiyuan Formation and Ordovician. The occurrence of water inrush can be avoided effectively by applying grouting reinforcement technology to the coal floor. However, the reinforcement treatment of the coal floor belongs to underground concealment engineering, and it is of great significance for the safe production of the coal mine by scientifically and comprehensively evaluating the technical method of the grouting effect on the working face floor. In this study, the optimal transfer matrix is used to construct the judgment matrix that meets the consistency requirements; the analytic hierarchy process is improved; and the grouting effect of the working face floor is evaluated by fuzzy comprehensive evaluation based on several factors of the grouting effect. Taking the grouting engineering of the 15092 working face of the Guhanshan Mine as an example, the evaluation of the grouting effect based on four evaluatory indices have been refined: dynamic hydrological features, grout amount, grouting inspection hole, and geophysical prospecting have been refined. Based on the improved analytic hierarchy process (AHP), the result of the grouting effect can be divided into four levels: distinction, good, average, and poor. The study would play a very important role in the evaluation of the grouting reinforcement of the working face floor and the practice of coal mine production safety.