Comparison of catalytic upgrading of biomass fast pyrolysis vapors over CaO and Fe(III)/CaO catalysts

Effects of Fe contents on fast pyrolysis of biomass with Fe/CaO catalysts

“…The wood sawdust was used as biomass material and the ultimate, proximate and component analyses of sawdust were shown in the literatures [15,16].…”

“…The schematic of Py-GC/MS equipment has been shown in our previous reports [15]. The chromatographic separation of the volatile products was performed using an Agilent HP-5 capillary column (30 m × 0.25 mm × 0.25 mm).…”

“…In our previous studies, we have reported that compared to CaO catalyst, the Fe/CaO catalysts showed higher activity in upgrading the biomass fast pyrolysis vapors, and the Fe/CaO catalyst prepared by the impregnation method was more effective in reducing the oxygenated compounds than the catalyst produced by the mechanical mixing method [15,16]. However, the effects of Fe contents on fast pyrolysis of biomass with Fe/CaO catalysts have not been researched.…”

UTILIZATION OF NATURAL IRON ORE FOR CATALYTIC REACTION OF (Pyroligneous acid) DERIVED FROM PALM KERNEL SHELLS

“…Zhang et al (2014) reported that the Fe(III)/CaO catalyst can reduce the number of oxygenated compounds in the upgrading process of biomass fast pyrolysis vapor. The catalyst has the ability to produce light phenols from heavy phenols without any methoxyl group and unsaturated C-C bonds on the side chain.…”

Product distribution and sulfur behavior in sewage sludge pyrolysis: Synergistic effect of Fenton peroxidation and CaO conditioning

“…For example, in the study of Abbasi-Atibeh and Yozgatligil [16], both of Ca(OH) 2 and Fe 2 O 3 can speed up the reaction rate of Turkish lignite during oxy-fuel combustion. Zhang et al [17] found that Ca 2 Fe 2 O 5 formed in Fe(III)/CaO catalyst might protect the CaO support and suppress the Fe(III) sintering in upgrading of biomass pyrolysis vapors. Asami and Ohtsuka [18] prepared three iron catalysts from FeCl 3 solution precipitated by using urea, Ca(OH) 2 and NH 3 /NH 4 Cl.…”