Compartmentalized desalination and salination by high energy density desalination seawater battery

Kim, Namhyeok; Park, Jeong-Sun; Harzandi, Ahmad M.; Kishor, Koshal; Ligaray, Mayzonee; Cho, Kyung Hwa; Kim, Young‐Sik

doi:10.1016/j.desal.2020.114666

Cited by 39 publications

(32 citation statements)

References 38 publications

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“…A proof-of-concept of this complete SWB-D system was proposed in the year 2018 [5] and was successfully demonstrated in the previous study. [7] It is worth mentioning here that nomenclatures of cathode and anode in SWB-D system are opposite to those in other electrochemical desalination technologies such as capacitive deionization and electrodialysis (ED). For example, sodium ions are attracted to the anode in SWB-D system, whereas those are adsorbed onto the cathode in other systems.…”

Section: Seawater Battery Desalination System: Energy Storage System During Desalinationmentioning

confidence: 99%

“…It is a multi‐functional process as it simultaneously stores electricity induced by sodium ion movement while removing salt ions from seawater. [ 5 , 6 , 7 , 8 ] So far, the cost for unit desalinated water from SWB‐D remains unexplored. This is primarily due to the lack of information from previous literatures regarding the energy prices of stand‐alone SWBs.…”

Section: Introductionmentioning

confidence: 99%

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Simultaneous Energy Storage and Seawater Desalination using Rechargeable Seawater Battery: Feasibility and Future Directions

et al. 2021

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Rechargeable seawater battery (SWB) is a unique energy storage system that can directly transform seawater into renewable energy. Placing a desalination compartment between SWB anode and cathode (denoted as seawater battery desalination; SWB-D) enables seawater desalination while charging SWB. Since seawater desalination is a mature technology, primarily occupied by membrane-based processes such as reverse osmosis (RO), the energy cost has to be considered for alternative desalination technologies. So far, the feasibility of the SWB-D system based on the unit cost per desalinated water ($ m −3 ) has been insufficiently discussed. Therefore, this perspective aims to provide this information and offer future research directions based on the detailed cost analysis. Based on the calculations, the current SWB-D system is expected to have an equipment cost of ≈1.02 $ m −3 (lower than 0.60-1.20 $ m −3 of RO), when 96% of the energy is recovered and stable performance for 1000 cycles is achieved. The anion exchange membrane (AEM) and separator contributes greatly to the material cost occupying 50% and 41% of the total cost, respectively. Therefore, future studies focusing on creating low cost AEMs and separators will pave the way for the large-scale application of SWB-D.

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Section: Seawater Battery Desalination System: Energy Storage System During Desalinationmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Simultaneous Energy Storage and Seawater Desalination using Rechargeable Seawater Battery: Feasibility and Future Directions

et al. 2021

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“…Especially, the buoy application is interested in its usage time [16], but there are still some issues to be resolved in these previous works. Firstly, it requires proper methods to support the state of charge (SOC) estimation function [17]- [21]. The SWB cell voltage during operations changes in proportion to the amount of charge or discharge since Na+ ions of seawater move to the inside of the anode to form Na metal during the charging process [17].…”

Section: Introductionmentioning

confidence: 99%

“…Firstly, it requires proper methods to support the state of charge (SOC) estimation function [17]- [21]. The SWB cell voltage during operations changes in proportion to the amount of charge or discharge since Na+ ions of seawater move to the inside of the anode to form Na metal during the charging process [17]. However, even if the amount of charge increases, only the amount of Na metal increases and the state of the material does not change [18].…”

Section: Introductionmentioning

confidence: 99%

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Seawater Battery-Based Wireless Marine Buoy System With Battery Degradation Prediction and Multiple Power Optimization Capabilities

Cho

Kim

et al. 2021

IEEE Access

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This paper presents a wireless marine buoy system based on the seawater battery (SWB), providing self-powered operation, power-efficient management, and degradation prediction and fault detection. Since conventional open circuit voltage (OCV) methods cannot be applied due to inherent cell characteristics of SWB, the coulomb counting (CC) method is adopted for the state of charge (SOC) monitoring. For the state of health (SOH), a variance-based detection scheme is proposed to provide degradation prediction and fault detection of the SWB. The self-powered operation is augmented by two proposed power optimization schemes such as multiple power management and three-step LED light control. A wireless buoy system prototype is manufactured, and its functional feasibility is experimentally verified, where its location and SOC are periodically monitored in a smartphone-based wireless platform.

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Na₃Zr₂Si₂PO₁₂ Solid Electrolyte Membrane for High‐Performance Seawater Battery

Dixit

Essehli

et al. 2023

Advanced Science

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Seawater batteries (SWBs) have gained tremendous interest in the electrochemical energy storage research field because of their low cost, natural abundance, and potential use for long-duration energy storage. Advancing a SWB to demonstration projects is plagued by the poor electrochemical performance stemming from the poor interfaces of the solid electrolyte (SE), as well as the structural and chemical instabilities and sluggish ionic transport properties. In this study, the anode compartment of a surrogate SWB is constructed with a Na | SE | hard carbon configuration, and tailored dopants are introduced into the Nasicon-type Na 3 Zr 2 Si 2 PO 12 (NZSP) SE membrane. After doping with TiO 2 , a much more densely packed pellet with uniformly distributed porous structure is obtained. Changes in surface chemistry and local structure in the bulk are observed, which are believed to contribute to the improved ionic conductivity and higher critical current density of the TiO 2 -doped NZSP. Stable cycling performance with reversible capacities based on different Na storage mechanisms are also demonstrated.

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Compartmentalized desalination and salination by high energy density desalination seawater battery

Cited by 39 publications

References 38 publications

Simultaneous Energy Storage and Seawater Desalination using Rechargeable Seawater Battery: Feasibility and Future Directions

Simultaneous Energy Storage and Seawater Desalination using Rechargeable Seawater Battery: Feasibility and Future Directions

Seawater Battery-Based Wireless Marine Buoy System With Battery Degradation Prediction and Multiple Power Optimization Capabilities

Na₃Zr₂Si₂PO₁₂ Solid Electrolyte Membrane for High‐Performance Seawater Battery

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Compartmentalized desalination and salination by high energy density desalination seawater battery

Cited by 39 publications

References 38 publications

Simultaneous Energy Storage and Seawater Desalination using Rechargeable Seawater Battery: Feasibility and Future Directions

Simultaneous Energy Storage and Seawater Desalination using Rechargeable Seawater Battery: Feasibility and Future Directions

Seawater Battery-Based Wireless Marine Buoy System With Battery Degradation Prediction and Multiple Power Optimization Capabilities

Na3Zr2Si2PO12 Solid Electrolyte Membrane for High‐Performance Seawater Battery

Contact Info

Product

Resources

About

Na₃Zr₂Si₂PO₁₂ Solid Electrolyte Membrane for High‐Performance Seawater Battery