Design of nanodevices with low power
consumption and high performance
is highly desirable. Recently, a band-to-band tunneling field effect
transistor (TFET) is developed, which offers an opportunity to overcome
the thermal subthreshold limit. In this work, we demonstrate that
two-dimensional (2D) main-group metal chalcogenides possess small
effective masses and suitable band edge positions, which show potentials
for TEFT devices. Then, we take GeS/SnS2-1T and GaTe-2H/SnSe2-1T van der Waals (vdW) heterostructures as examples and investigate
their electronic properties under various electric fields. We find
that these vdW heterostructures composed of main-group metal chalcogenides
can transfer from type-II to type-III band alignment if a positive
electric field is applied. In addition, the systems show a negative
differential resistance (NDR) effect, which could be further enhanced
if we lift the gate voltage. The simulated charge currents could be
up to the order of μA, making them promising candidates for
future TFET devices. Thus, our work provides a useful guideline for
the design of 2D nanodevices for tunneling applications.