This study identified the key chemical components based on an analysis of the seasonal variations of ground level PM 2.5 concentrations and its major chemical constituents (sulfate, nitrate, ammonium, organic carbon, and elemental carbon) in the Seoul Metropolitan Area (SMA), over a period of five years, ranging from 2012 to 2016. It was found that the mean PM 2.5 concentration in the SMA was 33.7 µg/m 3 , while inorganic ions accounted for 53% of the total mass concentration. The component ratio of inorganic ions increased by up to 61%-63% as the daily mean PM 2.5 concentration increased. In spring, nitrate was the dominant component of PM 2.5 , accounting for 17%-32% of the monthly mean PM 2.5 concentrations. In order to quantify the impact of long-range transport on the SMA PM 2.5 , a set of sensitivity simulations with the community multiscale air-quality model was performed. Results show that the annual averaged impact of Chinese emissions on SMA PM 2.5 concentrations ranged from 41% to 44% during the five years. Chinese emissions' impact on SMA nitrate ranged from 50% (winter) to 67% (spring). This result exhibits that reductions in SO 2 and NO X emissions are crucial to alleviate the PM 2.5 concentration. It is expected that NO X emission reduction efforts in China will help decrease PM 2.5 concentrations in the SMA.