Conductive metal organic framework mediated Sb nanoparticles as high-capacity anodes for rechargeable potassium-ion batteries

Nazir, Aqsa; Hằng, Lê Thị Thu; Nguyen, An‐Giang; Kim, Jaekook; Park, Chan‐Jin

doi:10.1016/j.cej.2022.138408

Cited by 38 publications

(16 citation statements)

References 60 publications

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“…After the second cycle, the charge curve differed from the first and exhibited two potential plateaus at around 0.6 and 0.3 V vs K + / K, corresponding to KSb and K 3 Sb formation, respectively. 47,48 The discharge capacity increased with each cycle due to FeSb 2 activation, which was confirmed in an organic-solventbased electrolyte. 30 The CE values exceeded 99.0% in the sixth cycle and reached 99.9% in the 32nd cycle.…”

Section: Potassiation and Depotassiation Propertiesmentioning

confidence: 61%

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Anode Properties of Sb-Based Alloy Electrodes for K-Ion Batteries in an Ionic-Liquid Electrolyte

Domi,

Usui,

Kuritani

et al. 2023

ACS Appl. Energy Mater.

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Maintaining the sustainability of society demands the strategic use of multipurpose rechargeable batteries. One promising option is K-ion batteries (KIBs), which are suitable as large stationary storage batteries and store renewable energy because of their abundant K resources. Herein, the anode properties of different binary antimonide (MSb x ; M: metal) electrodes were investigated for KIBs in an ionic-liquid electrolyte. The results indicated that although Sb and SnSb electrodes exhibited a high initial reversible capacity, their cycle stability was poor. In contrast, rare-earth antimonide (LaSb, SmSb, and YSb) electrodes showed extremely long cycle stability over 500 cycles with a capacity approximately one-third that of the Sb electrode. Interestingly, rare-earth antimonides possess seamless alloying and dealloying with K without undergoing phase separation into rare-earth and Sb phases. Additionally, other MSb x electrodes, such as FeSb2, FeSb, and AlSb, exhibited relatively higher reversible capacity and cycle stability when M was K-inactive. These electrodes possessed moderate Mohs hardness and low electrical resistance and caused MSb x phase separation into M and Sb phases. Notably, the stiff M phase effectively withstood the compressive stress produced by Sb and provided a supporting skeleton. Our study will provide insight into the physicochemical properties of M alloyed with Sb to achieve excellent cycle stability in KIBs and reveal that the same active material demonstrated different anode properties than Na-ion batteries.

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Section: Potassiation and Depotassiation Propertiesmentioning

confidence: 61%

“…The potential plateau at approximately 0.2 V vs K + /K was attributed to the potassiation of FeSb 2 . After the second cycle, the charge curve differed from the first and exhibited two potential plateaus at around 0.6 and 0.3 V vs K + /K, corresponding to KSb and K 3 Sb formation, respectively. , …”

Section: Resultsmentioning

confidence: 93%

Anode Properties of Sb-Based Alloy Electrodes for K-Ion Batteries in an Ionic-Liquid Electrolyte

Domi,

Usui,

Kuritani

et al. 2023

ACS Appl. Energy Mater.

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“…Renewable organic matter extracted from nature has a wide range of applications as organic electrode materials. Their degradation will not pollute the environment and they may replace metal ions as active substances such as covalent organic framework (COF) based organic materials, 17,18 biomass small molecules, 19,20 metal-organic frameworks (MOF), 21,22 organic polymers, 23,24 and so on. Dopamine, the most abundant catecholamine neurotransmitter in biology, is used to help cells transmit impulses, as well as used in ion storage and electron conduction in batteries.…”

Section: Introductionmentioning

confidence: 99%

In situ quantitative polymerization of dopamine on dual functional carbon nanotubes as high stability and rate capacity anodes for potassium ion storage

Yin

et al. 2023

Nanoscale

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“…(2) low redox potential of −0.66 V (vs. standard hydrogen electrodes) in alkaline solutions, and (3) low cost (~$7/kg). [6][7][8] Moreover, Sb anode in alkaline electrolytes relies on the transformation of SbO 2 − /Sb for energy storage, 9,10 ensuring fast reaction kinetics. As opposite to Zn anode, [11][12][13][14][15] Sb exhibits dendrite-free deposition behavior.…”

Section: Introductionmentioning

confidence: 99%

Carbon‐anchored Sb nanoparticles as high‐capacity and stable anode for aqueous alkaline batteries

Qin

Shi

et al. 2023

Battery Energy

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Antimony (Sb) holds a high theoretic capacity and suitable redox potential as a promising anode for aqueous alkaline batteries (AABs). However, the uncontrollable nucleation for SbO2− and promiscuous water‐induced side reactions severely degrade the reversibility of Sb anode. Herein, the carbon‐anchored Sb nanoparticles are constructed to induce uniform Sb plating/stripping for high‐performance AABs. The experimental results reveal that the enhanced interaction between carbon and antimony as well as defective carbon can significantly improve the electrical conductivity and decrease the Sb nucleation overpotential. Accordingly, the as‐prepared Sb anode enables preferential plating of Sb rather than parasitic side reactions. As a result, the cycle life of A‐Sb/CF is sustained over 500 cycles at 10 mA cm−2/2 mAh cm−2. Even at the high capacity of 4 mAh cm−2, this anode can cycle stably for 225 cycles, which is significantly better than the Sb/CF counterpart. Furthermore, the assembled Ni3S2@Ni(OH)2//A‐Sb/CF full battery demonstrates a high capacity of 2.17 mAh cm−2 and a stable cycle life of over 500 cycles.

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Conductive metal organic framework mediated Sb nanoparticles as high-capacity anodes for rechargeable potassium-ion batteries

Cited by 38 publications

References 60 publications

Anode Properties of Sb-Based Alloy Electrodes for K-Ion Batteries in an Ionic-Liquid Electrolyte

Anode Properties of Sb-Based Alloy Electrodes for K-Ion Batteries in an Ionic-Liquid Electrolyte

In situ quantitative polymerization of dopamine on dual functional carbon nanotubes as high stability and rate capacity anodes for potassium ion storage

Carbon‐anchored Sb nanoparticles as high‐capacity and stable anode for aqueous alkaline batteries

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