Contributions to the chemistry of silicon-sulphur compounds—LX. Synthesis, molecular structure and properties of the dimeric cadmium(II) bis(tri-tert-butoxysilanethiolate) (t-C4H9O)3SiS2Cd2

Structural Variety of Cobalt(II), Nickel(II), Zinc(II), and Cadmium(II) Complexes with 4,4′‐Azopyridine: Synthesis, Structure and Luminescence Properties

“…Tri-tert-butoxysilanethiol, [Co{SSi(OtBu) 3 } 2 (NH 3 )] 2 ,a nd [Cd{SSi(Ot-Bu) 3 } 2 ] 2 were synthesized as reported previously. [49][50][51] All other starting materials were obtained from commercial sources and were used without further purification. Elemental analyses (C, H, N, and Sc ontents) were performed with an Elemental Analyser EA 1108 (Carlo Erba Instruments).…”

Cadmium complex possessing simultaneously silanethiolato- and dithiocarbamato-ligands. A novel single-source precursor of cadmium sulfide

“…Dimeric bis(tri-tertbutoxysilanethiolato)cadmium(II) complex was prepared as described elsewhere [21]. Ammonium N,N-tetrametylenedithiocarbamate, C 4 H 8 NCS 2 NH 4 (Fluka), and other commercially available chemicals were used as received.…”

(2,2′-Bipyridine)bis(tri-tert-butoxysilanethiolato-κ2O,S)cadmium(II)

“…Crystals of (I) suitable for X-ray measurements were obtained according to a previously described procedure (Wojnowski et al, 1992). The compound is very stable and may be stored for years without decomposition.…”

“…Previously we described the preparation of a dimeric cadmium silanethiolate [Cd{SSi(OBu t ) 3 } 2 ] 2 and its reactions with 2,2 0bipyridine or 1,10-phenanthroline giving complexes of a formal [Cd(L){SSi(OBu t ) 3 } 2 ] stoichiometry, where L = bipy (I) or phen (Wojnowski et al, 1992); however, structural work was not carried out. Subsequently, we obtained a related Zn complex, [Zn(bipy){SSi(OBu t ) 3 } 2 ], (II), and found that Zn is in a distorted tetrahedral environment within a ZnN 2 S 2 core (Becker et al, 1996).…”