The nonlinear behavior of the electron effective mass in degenerately doped n‐Si(P) under high uniaxial pressure X || [111] was observed in the range of the strain‐induced transition from metallic‐ to activation‐type conductivity. The relative contribution of the quadratic term in the effective mass vs. pressure dependence increases with doping. For just metallic crystals of n‐Si(P) the electron effective mass increase is described by only a single quadratic term. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)