Developing a structured catalyst was performed successfully, and
carbon-coated aluminum foam-supported ruthenium catalysts were prepared.
Seven different characterization techniques such as scanning electron
microscopy, transmission electron microscopy, X-ray photoelectron
spectroscopy, temperature-programmed reduction, inductively coupled
plasma-mass spectrometry, carbon monoxide chemisorption, and nitrogen
physisorption were applied on the solid catalysts. The carbon-coated
foams were checked for their mechanical stability, and the results
indicated that the foam catalysts were mechanically stable. The Ru/C
foam catalysts were used in a multiphase reactor setup, which had
six tubular reactors working in parallel. Continuous hydrogenation
of d-glucose, l-arabinose, and a mixture of l-arabinose and d-galactose was studied in the experimental
setup. Through investigating different reaction parameters, the temperatures
100–110 °C and the liquid flow rates 0.5–1 mL/min
were found to be suitable for catalyst screening and activity testing.
The experiments were carried out at 20 bar hydrogen pressure. The
continuous hydrogenation experiments were successful, the reproducibility
was good, and the foam catalysts were stable. High selectivities of
the desired products, sugar alcohols and sugar alcohol mixtures, were
obtained.