La 12x Sr x MnO 3 (LSMO) (x 0-0.3) films were prepared on SrTiO 3 (001) substrates by the dipping-pyrolysis process using metal naphthenates as starting materials. Epitaxially grown LSMO films were obtained by heat treatment at 800-1200 ± C; the fluctuation of alignment of these films, evaluated by reciprocal-space mapping of asymmetric x-ray diffraction, was markedly small, as comparable to that of the substrates. The LSMO films with x 0.1 -0.3 showed metallic conduction behavior at 25-300 K, and the resistivity was as low as that of LSMO single crystals, e.g., 4.5 3 10 24 V ? cm at 150 K for the film with x 0.3.