Exploitation of metallic glass as new brazing filler for Ti-based biomedical alloy was attempted. Ni 10 P 20 joint showed the excellent properties in terms of both corrosion resistance and tensile strength, which were superior to a joint brazed using Ti-15Cu-25Ni conventional filler. X-ray tomograph indicates that fracture tends to occur in the vicinity of the brazing interface after tensile test.The brazed metallic glass fillers were fully crystallized, excluding Pd 40 Cu 30 Ni 10 P 20 filler. Pd 40 Cu 30 Ni 10 P 20 brazed filler contained mapleleaf like primary dendrite, peritectoid and a few microns interfacial reaction layer in glassy matrix. The results indicated that Pd 40 Cu 30 Ni 10 P 20 is promising brazing filler for dental or biomaterial devices.