2004
DOI: 10.1016/j.polymdegradstab.2003.09.010
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Decomposition reactions of plastic model compounds in sub- and supercritical water

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Cited by 48 publications
(9 citation statements)
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“…The first is batch or flow apparatus used extensively in phase equilibria, thermodynamic analysis, kinetics, and salt or catalysts effect for organic matter in H-P and -T water, which measures after reaction [18][19][20][21][22][23][24][25][26]. The disadvantage of the method is that we cannot obtain in situ transformation to understand phase change and reaction mechanism of high pressure and temperature.…”
Section: Introductionmentioning
confidence: 99%
“…The first is batch or flow apparatus used extensively in phase equilibria, thermodynamic analysis, kinetics, and salt or catalysts effect for organic matter in H-P and -T water, which measures after reaction [18][19][20][21][22][23][24][25][26]. The disadvantage of the method is that we cannot obtain in situ transformation to understand phase change and reaction mechanism of high pressure and temperature.…”
Section: Introductionmentioning
confidence: 99%
“…Water acted not only as the reaction medium, but also as a reactant, causing the oxidation of methylene groups. Shibasaki et al [116] degraded aromatic ethers in sub-and supercritical water between 250 and 430°C. Na 2 CO 3 was present as a catalyst.…”
Section: Chemolysis and Solvent Processesmentioning
confidence: 99%
“…The gasification of waste plastic in supercritical water also attracted much attention. Supercritical water gasification of waste plastics and the model compounds (such as polyethylene) were investigated by many researchers (Watanabe et al, 1998;Watanabe et al, 2001;Shibasaki et al, 2004;Su et al, 2004;Takeshita et al, 2004;Su et al, 2007). The anaerobic organic wastewater from wheat straw includes acids (acetic acid, butyric acid) and ethanol etc.…”
Section: Organic Wastesmentioning
confidence: 99%