Defect-enhanced selective ion transport in an ionic nanocomposite for efficient energy harvesting from moisture

Lv, Dong; Zheng, Shasha; Cao, Chunyan; Li, Kedi; Ai, Liqing; Li, Xin; Yang, Zhengbao; Xu, Zhengtao; Yao, Xi

doi:10.1039/d2ee00432a

Cited by 41 publications

(36 citation statements)

References 56 publications

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“…It is worth noting that the reduction in RH can generally induce the water desorption of the device, resulting in the decay of the electrical signal. Also, the saturation of water absorption in the device can retard the electrical output unless replenishment is conducted by drying out the moisture content in the device. , Therefore, such a gap period between each cycle of output and drying should be avoided in terms of enhancing the device performance. As such, besides prolonging a single cycle of output duration, efforts are also desired to address the above concerns.…”

Section: D Nanomaterials In Megsmentioning

confidence: 99%

“…(ii) Schematic illustration of the interaction with the cations dissociated from the IL films for the pristine ZIF-8 and the defected ZIF-8, respectively. Reprinted with permission from ref . Copyright 2022 Royal Society of Chemistry.…”

Section: D Nanomaterials In Megsmentioning

confidence: 99%

“…Besides the scheme of the streaming potential, a MOF was also reported as an assistant in enhancing ion diffusion under a concentration gradient. Recently, an outstanding current density of 1.5 mA cm –2 was demonstrated in a MOF/GO membrane, in which zinc ions and 2-methylimidazoe (2-Hmim) were in situ synthesized on the GO skeleton . The membrane was then calcined to introduce defects on the MOF nanoparticles.…”

Section: D Nanomaterials In Megsmentioning

confidence: 99%

“…Recently, an outstanding current density of 1.5 mA cm −2 was demonstrated in a MOF/GO membrane, in which zinc ions and 2-methylimidazoe (2-Hmim) were in situ synthesized on the GO skeleton. 92 The membrane was then calcined to introduce defects on the MOF nanoparticles. 1-Octyl-3-methylimidazolium chloride ionic liquid (IL) films were incorporated on the membrane as a mobile-ion donor.…”

Section: Metal−organic Framework (Mof)mentioning

confidence: 99%

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Two-Dimensional Nanomaterials for Moisture-Electric Generators: A Review

Feng

Zhu

et al. 2022

ACS Appl. Nano Mater.

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As an emerging candidate for a sustainable power supply, moisture-electric generators (MEGs) have attracted great attention in recent years. Unlike the conventional hydroelectric system, MEGs propose to harvest energy from ambient moisture, driven by either ion diffusion under a concentration gradient or the interaction between a solid–liquid interface governed by electrostatic theory. Two-dimensional (2D) nanomaterials, in particular hydrophilic graphene oxide (GO), have been considered as the most promising materials for high-performance MEGs owing to their unique structure and properties. In line with the development of 2D nanomaterials, the recent electrical output of a single MEG has been greatly raised from tens to hundreds of millivolts, which is capable of powering commercial electronics. Herein, we have reviewed the recent progress of 2D nanomaterials in MEGs. The mechanism of moisture-induced electricity generation and strategies for tailoring 2D nanomaterials to enhance the output performance of MEGs are discussed. The potential application of MEGs is also discussed in two categories: sensing and power supply. Finally, the existing challenges and the perspective of MEGs are proposed for future study.

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Section: D Nanomaterials In Megsmentioning

confidence: 99%

Section: D Nanomaterials In Megsmentioning

confidence: 99%

Section: D Nanomaterials In Megsmentioning

confidence: 99%

Section: Metal−organic Framework (Mof)mentioning

confidence: 99%

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Two-Dimensional Nanomaterials for Moisture-Electric Generators: A Review

Feng

Zhu

et al. 2022

ACS Appl. Nano Mater.

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“…The amount of moisture in the atmosphere is estimated to be 12,900 trillion liters, which is 6 times higher than the amount of water in the world’s rivers . Moisture-driven power generators (MPGs) utilize the vast and ubiquitous moisture in the atmosphere to produce electric energy. − When an MPG absorbs water molecules, oxygen-containing functional groups, such as carboxyl groups, dissociate to produce hydrogen ions. If there is a directional flow of adsorbed water or a gradient of oxygen-containing functional groups is preformed between two collecting electrodes, a potential difference occurs in MPG, and an electric current is generated by the movement of electrons through the external wire. − …”

Section: Introductionmentioning

confidence: 99%

Performance Enhancement of Moisture-driven Power Generators by Photofragmentation of Inorganic Salt Particles

Eun

Jeon

2022

ACS Appl. Mater. Interfaces

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We developed a novel method based on the photofragmentation of inorganic salt particles for improving the moisture-electric energy transformation performance of a moisturedriven power generator (MPG). Infrared laser irradiation on cellulose nanofiber films (CNFs) prepared by a TEMPO (2,2,6,6tetramethylpiperidine-1-oxyl radical)-mediated oxidation of bleached pulp induced a photothermal conversion of CNFs to porous graphitic carbon films (GCFs) with the catalyst-derived Na 2 O 2 particles. Since the laser beam was focused on the top surface of CNF, the gradients of the photothermal conversion of CNFs and Na 2 O 2 concentration were created along the thickness direction. Subsequent irradiation with ultraviolet (UV) light induced the photofragmentation of the micrometer-sized Na 2 O 2 particles into smaller ones, which increased the surface area of the salt particles in contact with the GCFs and consequently increased the number of effective dissociable charge carriers. When the GCF was exposed to moisture, the dissociated sodium ions migrated along the preformed concentration gradient, producing continuous outputs of current and voltage. At 90% relative humidity, the maximum voltage and current density outputs of the MPG increased from 0.91 V and 18.7 μA/cm 2 before UV irradiation to 1.10 V and 56.2 μA/cm 2 after UV irradiation, respectively. Additionally, we demonstrated that a green light-emitting diode could be turned on without capacitors or rectifiers during normal breathing while wearing a face mask with three GCF arrays attached (each 3 mm × 3 mm × 0.1 mm in size).

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Moist‐Electric Generator with Efficient Output and Scalable Integration Based on Carbonized Polymer Dot and Liquid Metal Active Electrode

Qin

Cheng

et al. 2023

Adv Funct Materials

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Moisture-enabled electricity generation (MEG) is highly promising in nextgeneration energy conversion. However, the practical applications of existing MEG devices are limited due to their low current and voltage outputs, strong dependence on high moisture, and inflexible nature. Herein, an efficient MEG integrated with flexible, all-weather, and scalable fabrication characteristics based on the rational combination of carbonized polymer dots (CPDs) and liquid metal (LM) active electrodes is developed for the first time. Remarkably, the fabricated MEG device can produce a stable voltage output of 800 mV and a record high current density of 1640 µA cm −2 . Even at a low air humidity of 15%, the MEG device can provide a high voltage output of 0.65 V and a considerable current density of 12 µA cm −2 . The prompted diffusion of hydrogen ions in CPDs and the additional metal ions ionized from the LM electrode contribute synergistically to the high electricity generation. Additionally, the device can be easily integrated on various flexible substrates and generate an ultrahigh voltage of 210 V to power commercial electronics, showing great potential in large-scale fabrication and application.

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Defect-enhanced selective ion transport in an ionic nanocomposite for efficient energy harvesting from moisture

Abstract: Defect-enhanced selective ion transport within a generator made from an ionic liquid film supported by ZIF-8-based membranes enables high-performance moisture energy harvesting.

Cited by 41 publications

References 56 publications

Two-Dimensional Nanomaterials for Moisture-Electric Generators: A Review

Two-Dimensional Nanomaterials for Moisture-Electric Generators: A Review

Performance Enhancement of Moisture-driven Power Generators by Photofragmentation of Inorganic Salt Particles

Moist‐Electric Generator with Efficient Output and Scalable Integration Based on Carbonized Polymer Dot and Liquid Metal Active Electrode

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