Dehydrogenation of propane on chromia/alumina catalysts promoted by tin

Cabrera, Franklin; Ardissone, Daniel Enrique; Gorriz, Osvaldo F.

doi:10.1016/j.cattod.2007.12.039

Cited by 40 publications

(19 citation statements)

References 13 publications

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“…In all cases, the addition of tin improves the initial selectivity of the catalysts. 21 Jean-Marie Herrmann et al prepared and characterized Mo-Sn-O systems by Raman spectroscopy and electrical conductivity measurements. The authors found that four-coordinated species are dispersed at the external surface while six-coordinated species are occluded through coalescence of molybdate layers.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Characterizations of SnO<SUB>2</SUB> Nanoparticles

Ayeshamariam¹,

Vidhya²,

Sivaranjani³

et al. 2013

Journal of Nanoelectronics and Optoelectronics

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SnO 2 powder particles have been studied intensively as one of the best gas sensing materials because they exhibit very good sensitivity, selectivity and reproducibility due to their nano-grained microstructure, larger specific area and the presence of oxygen vacancies in the lattice. With the aim to produce nanocrystalline oxide powders through a simple and inexpensive route, the sol-gel combustion process has been selected to prepare SnO 2 powder in the present study. The prepared powders were characterized for their structural, morphological, electrical and gas sensor properties for ethanol. Crystal density, lattice volume and microstrain are found to be nearly constant with annealing temperature, which confirm the formation of monophase SnO 2 . Spherical particles in the nanoscale level, with the size increasing with temperature are observed from XRD result. Sensor studies show high resistance of SnO 2 pellets, which can be changed under different gaseous atmospheres and becoming a good candidate for gas sensing application.

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Section: Introductionmentioning

confidence: 99%

Synthesis and Characterizations of SnO<SUB>2</SUB> Nanoparticles

Ayeshamariam¹,

Vidhya²,

Sivaranjani³

et al. 2013

Journal of Nanoelectronics and Optoelectronics

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“…Dehydrogenation of propane has great industrial importance owing to obtaining propylene from low cost propane feedstock for polymerization and other organic synthesis ,. Dehydrogenation of propane (PDH) and oxidative dehydrogenation (ODH) of propane have been developed as the new propylene producing technologies ,.…”

Section: Introductionmentioning

confidence: 99%

One‐Pot Preparation of Ni₂P/γ‐Al₂O₃ Catalyst for Dehydrogenation of Propane to Propylene

et al. 2018

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The γ‐Al2O3 supported Ni2P catalysts for propane dehydrogenation were prepared by one‐pot method and evaluated to study the platinum‐like behaviour of Ni2P. The catalysts were characterized by X‐ray diffraction (XRD), Scanning Electron Microscope (SEM), Energy‐dispersive X‐ray Spectrometer (EDS), N2 adsorption at −196 oC and temperature‐programmed desorption of ammonia (NH3‐TPD). Results show that Ni2P is beneficial to the catalytic stability. It exhibits higher conversion for PDH of 23.8% and propylene selectivity of 74.4%.

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“…Both 2CoAl and 5CoAl manifested three bands with maxima at around 540, 590, 630 nm ascribing to tetrahedral Co 2? ions [24][25][26][27]. For 10CoAl, smaller amount of tetrahedral Co 2?…”

Section: The Nature Of Active Cobalt Species For Propylene Productionmentioning

confidence: 97%

Studies on the Nature of Active Cobalt Species for the Production of Methane and Propylene in Catalytic Dehydrogenation of Propane

Sun

Shan

et al. 2015

Catal Lett

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Co/Al 2 O 3 catalysts with different Co 3 O 4 loadings were studied in catalytic dehydrogenation of propane. The optimal results of 21.5 wt% propylene yield and 83.6 % selectivity were obtained at 5 wt% loading. XRD, DRS and XPS results showed that at loadings below 10 wt%, the ''surface Co spinel'' formed from tetrahedral Co 2? ions during the course of reaction constituted the active site for dehydrogenation reaction. Whereas at high loadings (above 10 wt%), only Co 3 O 4 crystallites presented, which were easily reduced to metallic Co species, resulting in dramatically enhanced cracking reaction and the formation of abundant methane. Graphical AbstractElectronic supplementary material The online version of this article (

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Dehydrogenation of propane on chromia/alumina catalysts promoted by tin

Cited by 40 publications

References 13 publications

Synthesis and Characterizations of SnO<SUB>2</SUB> Nanoparticles

Synthesis and Characterizations of SnO<SUB>2</SUB> Nanoparticles

One‐Pot Preparation of Ni₂P/γ‐Al₂O₃ Catalyst for Dehydrogenation of Propane to Propylene

Studies on the Nature of Active Cobalt Species for the Production of Methane and Propylene in Catalytic Dehydrogenation of Propane

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Dehydrogenation of propane on chromia/alumina catalysts promoted by tin

Cited by 40 publications

References 13 publications

Synthesis and Characterizations of SnO<SUB>2</SUB> Nanoparticles

Synthesis and Characterizations of SnO<SUB>2</SUB> Nanoparticles

One‐Pot Preparation of Ni2P/γ‐Al2O3 Catalyst for Dehydrogenation of Propane to Propylene

Studies on the Nature of Active Cobalt Species for the Production of Methane and Propylene in Catalytic Dehydrogenation of Propane

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One‐Pot Preparation of Ni₂P/γ‐Al₂O₃ Catalyst for Dehydrogenation of Propane to Propylene