Brittleness index is an important
parameter used to select favorable
fracturing intervals during shale gas exploitation. Mineral compositions
exert a significant influence on rock brittleness, and various grain
assemblages can be deposited under different paleo-environmental conditions.
The Wufeng–Longmaxi marine shale is a hot spot of shale gas
exploitation in China. However, for the Wufeng–Longmaxi shale,
the relationship between sedimentary environments, grain assemblages,
and shale brittleness are rarely discussed. To address these problems,
a series of experiments including petrographic observations, mineral
compositions, rock mechanics, and major (trace) element analyses were
carried out on shale samples from the Wufeng–Longmaxi formations.
The Wufeng–Longmaxi formations are divided into upper Longmaxi
formation (ULMX), lower Longmaxi formation (LLMX), and Wufeng formation
(WF). The results show that WF shale samples deposited under a sedimentary
environment with low terrigenous detrital influx, suboxic depositional
water, and high paleoproductivity are characterized by the highest
energy-based BI, compared to ULMX and LLMX shale samples. Dolomite
in the samples grew in situ during early diagenesis. Redox conditions,
terrigenous detrital flux control authigenic carbonate contents, and
the oxic depositional water of the ULMX formation restrain carbonate
mineral formation. In contrast, the suboxic sedimentary environment
of the LLMX and WF allowed the generation of carbonate minerals. Compared
with the WF, the larger terrigenous detrital flux of LLMX formation
do favor more authigenic carbonate formation. The paleoproductivity
affects biogenic quartz generation, and abundant biogenic quartz,
primarily occurring in the form of micron-size microcrystalline quartz
in the shale matrix, and can connect the silt-size brittle minerals
to form a mechanical framework, which makes a strong positive contribution
to shale brittleness. Terrigenous detrital influx decreases brittleness
because the weakening effect of terrigenous clay minerals on shale
brittleness is greater than the strengthening effect of terrigenous
brittle minerals on shale brittleness.