In communities with
household solid fuel use, transitioning to
clean stoves/fuels often results in only moderate reductions in fine
particulate matter (PM
2.5
) exposures; the chemical composition
of those exposures may help explain why. We collected personal exposure
(men and women) and outdoor PM
2.5
samples in villages in
three Chinese provinces (Shanxi, Beijing, and Guangxi) and measured
chemical components, including water-soluble organic carbon (WSOC),
ions, elements, and organic tracers. Source contributions from chemical
mass balance modeling (biomass burning, coal combustion, vehicles,
dust, and secondary inorganic aerosol) were similar between outdoor
and personal PM
2.5
samples. Principal component analysis
of organic and inorganic components identified analogous sources,
including a regional ambient source. Chemical components of PM
2.5
exposures did not differ significantly by gender. Participants
using coal had higher personal/outdoor (P/O) ratios of coal combustion
tracers (picene, sulfate, As, and Pb) than those not using coal, but
no such trend was observed for biomass burning tracers (levoglucosan,
K
+
, WSOC). Picene and most levoglucosan P/O ratios exceeded
1 even among participants not using coal and biomass, respectively,
indicating substantial indirect exposure to solid fuel emissions from
other homes. Contributions of community-level emissions to exposures
suggest that meaningful exposure reductions will likely require extensive
fuel use changes within communities.