Determination of Biosorption Mechanism in Biomass of Agave, Using Spectroscopic and Microscopic Techniques for the Purification of Contaminated Water

Hernández-Botello, M.T.; Barriada, José L.; Vicente, Manuel E. Sastre de; Mendoza-Pérez, Jorge A.; Chanona-Pérez, Jorge; López-Cortez, M. S.; Téllez‐Medina, Darío Iker

doi:10.24275/rmiq/ia501

Cited by 5 publications

(6 citation statements)

References 18 publications

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“…Adsorption experiments were carried out by preparing 10 MB solutions at different concentrations (25,50,75,100,125,150,175,200,225, and 250 ppm) [3,8,27]. en, 0.1 g of the adsorbents (nance seeds and peels) was added, and pH was adjusted to 7 and 10 to simulate urban and industrial (textile) effluents [28].…”

Section: Methylene Blue Adsorption Experimentsmentioning

confidence: 99%

“…Values for R La indicate various nature of isotherms such as irreversible (R La � 0), favorable (0 < R La < 1), linear (R La �1), or unfavorable (R La > 1). Efficiency of adsorption η was evaluated in all cases as [8] η…”

Section: Methylene Blue Adsorption Experimentsmentioning

confidence: 99%

“…For instance, waste biomass of Phaseolus vulgaris has been used for the removal of lead (II) ions [5], and its husks were used as adsorbent for Cr (VI) removal [6,7]. Agave biomass has been employed as a biosorbent for lead (Pb II) and copper (Cu II) from contaminated water [8]. Additionally, soybean and rice hulls were utilized for the adsorption of Hg from dilute aqueous solutions [9].…”

Section: Introductionmentioning

confidence: 99%

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Removal of Methylene Blue from Aqueous Solutions by Using Nance (Byrsonima crassifolia) Seeds and Peels as Natural Biosorbents

Robles-Melchor

Cornejo-Mazón

Hernández-Martínez

et al. 2021

Journal of Chemistry

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Contamination of effluents with chemicals is a serious problem that impacts human health. Methylene blue is a cationic dye found frequently in industrial and urban sewages. In this work, dried grinded seeds and peels of nance were used as biosorbents in aqueous solutions at pH 7 and 10 (simulating urban and textile effluents) finding that Langmuir and Freundlich isotherms adequately described the sorption. Adsorption efficiencies were larger than 98% in all cases and slightly lower at pH 7 due to the closeness with the point of zero charge (pzc) of seeds and peels of nance (5.96 and 3.42, respectively). In all cases, Langmuir adsorption was favorable (RLa < 1), and Gibbs free energy of adsorption was negative indicating spontaneity, and since these values were larger than −80 but lower than 0 kJ/mol, the MB removal process was mainly due to physical interactions, a characteristic of physical adsorption. No significant differences were found amongst bulk mass transfer coefficients for the adsorption of both sorbents, indicating that both bioadsorbents had the same hydrodynamic and driving forces as well as depicted similar MB-adsorbent affinities. Interaction of MB with adsorbents was corroborated by FTIR spectroscopy, and the sorption was evidenced by scanning electron microscopy and image analysis which indicated that both adsorbents had fractal structures.

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Section: Methylene Blue Adsorption Experimentsmentioning

confidence: 99%

Section: Methylene Blue Adsorption Experimentsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Removal of Methylene Blue from Aqueous Solutions by Using Nance (Byrsonima crassifolia) Seeds and Peels as Natural Biosorbents

Robles-Melchor

Cornejo-Mazón

Hernández-Martínez

et al. 2021

Journal of Chemistry

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“…The current study evidences the utility of the CLSM technique for corroborating the uptake of a sorbate on a biosorbent. To date, few reports exist on the use of this technique to examine the sorption of heavy metals [58,59,60] and dyes [61].…”

Section: Clsm Analysismentioning

confidence: 99%

Biosorptive removal of acid orange 74 dye by HCl-pretreated Lemna sp.

et al. 2020

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Acid orange 74 (AO74) is a chromium-complex monoazo acid dye widely used in the textile industry. Due to being highly toxic and non-biodegradable, it must be removed from polluted water to protect the health of people and the environment. The aim of this study was twofold: to evaluate the biosorption of AO74 from an aqueous solution by utilizing HCl-pretreated Lemna sp. (HPL), and to examine dye desorption from the plant material. The maximum capacity of AO74 biosorption (64.24 mg g-1) was reached after 4 h at the most adequate pH, which was 2. The biosorption capacity decreased 25% (to 48.18 mg g-1) during the second biosorption/desorption cycle and remained essentially unchanged during the third cycle. The pseudo-second-order kinetics model concurred well with the experimental results of assays involving various levels of pH in the eluent solution and distinct initial concentrations of AO74. NaOH (0.01 M) was the best eluent solution. The Toth isotherm model best described AO74 biosorption equilibrium data. FTIR analysis confirmed the crucial role of HPL proteins in AO74 biosorption. SEM-EDX and CLSM techniques verified the effective biosorption/desorption of the dye during the three cycles. Therefore, HPL has potential for the removal of AO74 dye from wastewaters.

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“…Fig. 7 shows the band at 1560 cm −1 due to a carbonyl (Norhaniza Yusof et al, 2016;Hernández-Botello et al, 2020) or lactone groups (Andrade et al, 2018) formed by the interaction with atmospheric oxygen during the calcination process, which allows the formation of covalent bonds between the ACFF carbonyl group and the cationic species of MB (Salazar-Rabago et al, 2017). After second adsorption process, MB removed is turned to CO and CO 2 which allows covalent binding between ACFF surface and these degradation products, therefore, the only band in the FTIR spectra shows that more carbonaceous material were formed after calcination process due at high temperature used.…”

Section: Chemical Structure Propertiesmentioning

confidence: 99%

Effect of thermal treatment of activated carbon fiber felt for reuse in removal of methylene blue from a synthetic wastewater

Rojas-Valencia¹,

Flores²,

Reza-San-Germán³

et al. 2020

Rev.Mex.Ing.Quim.

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Determination of Biosorption Mechanism in Biomass of Agave, Using Spectroscopic and Microscopic Techniques for the Purification of Contaminated Water

Abstract: Modelado de la biodegradación en biorreactores de lodos de hidrocarburos totales del petróleo intemperizados en suelos y sedimentos (Biodegradation modeling of sludge bioreactors of total petroleum hydrocarbons weathering in soil and sediments)

Cited by 5 publications

References 18 publications

Removal of Methylene Blue from Aqueous Solutions by Using Nance (Byrsonima crassifolia) Seeds and Peels as Natural Biosorbents

Removal of Methylene Blue from Aqueous Solutions by Using Nance (Byrsonima crassifolia) Seeds and Peels as Natural Biosorbents

Biosorptive removal of acid orange 74 dye by HCl-pretreated Lemna sp.

Effect of thermal treatment of activated carbon fiber felt for reuse in removal of methylene blue from a synthetic wastewater

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