Determination of sulfonamide antibiotics in wastewater: A comparison of solid phase microextraction and solid phase extraction methods

Balakrishnan, Vimal K.; Terry, K. A.; Toito, J.

doi:10.1016/j.chroma.2006.07.011

Cited by 189 publications

(79 citation statements)

References 33 publications

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“…In contrast, SPE cartridges are one-time use only, significantly more solvent is necessary and high volumes of samples are percolated. However, regarding to the sensitivity and precision, SPE was found more sensitive and it showed better accuracy during extraction as well [29,34] which showed the preferable use of SPE for the extraction of complex matrices.…”

Section: Sample Pre-treatment and Extraction Proceduresmentioning

confidence: 96%

“…SPE offers some advantages over LLE such as improved selectivity, specificity and reproducibility, lower organic solvent consumption, shorter sample preparation time, and easier operation and the possibility of automation. Solid-phase microextraction (SPME) has been used in some cases [29,34,35].…”

Section: Sample Pre-treatment and Extraction Proceduresmentioning

confidence: 99%

“…Coupling of SPE procedures on-line with LC provided several advantages, such as reduction of the number of sample handling steps required, elimination the target loss by keeping in the cartridge from drying which results in recovery improvement and saving of the analytical time and minimization of the consumption of organic solvents for each analysis. SPME can be another option for the extraction of aqueous samples [29,34,35]. SPME is an extraction technique that uses a fused-silica fibre with a solid stationary phase that collects analytes of interest.…”

Section: Sample Pre-treatment and Extraction Proceduresmentioning

confidence: 99%

“…Table 3 is showing the recent procedures for SAs extraction from water samples in studies dealing only with the SAs determination. All of studies used Oasis HLB columns except one using cation-exchange sorbent [34]. SAs contain one basic amine group (-NH 2 ) and one acidic sulfonamide group (-SO 2 NH-) ( Fig.…”

Section: Tetracycline Antibioticsmentioning

confidence: 99%

“…Thus SAs are positively charged at acidic conditions at pH 2, neutral between pH 2 and 5, and negatively charged at alkaline conditions at pH above 5. Only two studies adjusted pH of sample to pH 3.0 or 3.4 respectively [34,57] and in the rest of studies pH adjustment was not reported. This is not usual when SPE and the interaction between the analytes and the sorbent of SPE columns are pH dependent.…”

Section: Tetracycline Antibioticsmentioning

confidence: 99%

See 4 more Smart Citations

An overview of analytical methodologies for the determination of antibiotics in environmental waters

Seifrtová¹,

Nováková²,

Lino³

et al. 2009

Analytica Chimica Acta

322

170

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a b s t r a c tThe widespread occurrence of antibiotics as contaminants in the aquatic environment has increased attention in the last years. The concern over the release of antibiotics into the environment is related primarily to the potential for the development of antimicrobial resistance among microorganisms. This article presents an overview of analytical methodologies for the determination of quinolone (Qs) and fluoroquinolone (FQs), macrolide (MLs), tetracycline (TCs), sulfonamide (SAs) antibiotics and trimethoprim (TMP) in different environmental waters. The analysis of these antibiotics has usually been carried out by high-performance liquid chromatography (HPLC) coupled to mass spectrometry (MS) or tandem mass spectrometry (MS/MS) and to a lesser extent by ultraviolet (UV) or fluorescence detection (FD). A very important step before LC analysis is sample preparation and extraction leading to elimination of interferences and prevention of matrix effect and preconcentration of target analytes.

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Section: Sample Pre-treatment and Extraction Proceduresmentioning

confidence: 96%

Section: Sample Pre-treatment and Extraction Proceduresmentioning

confidence: 99%

Section: Sample Pre-treatment and Extraction Proceduresmentioning

confidence: 99%

Section: Tetracycline Antibioticsmentioning

confidence: 99%

Section: Tetracycline Antibioticsmentioning

confidence: 99%

See 3 more Smart Citations

An overview of analytical methodologies for the determination of antibiotics in environmental waters

Seifrtová¹,

Nováková²,

Lino³

et al. 2009

Analytica Chimica Acta

322

170

View full text Add to dashboard Cite

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Environmental Applications of Solid Phase Microextraction Techniques

Montesdeoca-Esponda

Torres-Padrón

Sosa‐Ferrera

et al. 2015

Analytical Separation Science

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Miniaturization is a strategy employed in sample preparation that has gained much prominence in recent years due to the need to develop more efficient procedures that consume less solvent and time. The analysis of important families of contaminants, such as pesticides or polycyclic aromatic hydrocarbons ( PAH s), in liquid samples has traditionally been conducted using conventional techniques, such as liquid–liquid extraction ( LLE ) and solid‐phase extraction ( SPE ). Although SPE uses much less amount of solvent than LLE , the volume can still be significant, making both techniques expensive and environment‐unfriendly procedures. The miniaturization of sample preparation processes has led to a new generation of techniques with improved characteristics. Different solid‐phase microextraction ( SPME ) techniques, including fibers, stir bar sorptive extraction ( SBSE ) and thin‐film microextraction ( TFME ), and automated techniques, such as in‐tube solid‐phase microextraction ( IT ‐ SPME ), have allowed the determination of different families of contaminant compounds, including emerging compounds in complex environmental waters, such as seawater, groundwater, or superficial water. The emerging compounds are relatively unknown compounds that are not covered by the existing regulations; they are frequently detected in different environmental compartments in very low concentrations. For this reason, their analysis requires extraction, purification and preconcentration from the matrix and subsequent separation and detection systems that can measure these concentration levels. In this chapter, we review the most recent applications of microextraction techniques based on solid phase coupled to liquid chromatography ( LC ) for the determination of different emerging contaminants in several water environmental matrices.

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Determination of oxytetracycline hydrochloride in milk and egg white samples using Ru(bipy)₃²⁺–Ce(SO₄)₂ chemiluminescence

et al. 2019

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A novel, rapid and sensitive chemiluminescence (CL) method for the determination of oxytetracycline hydrochloride (OTCH) is described in this paper. The presented method was based on the fact that OTCH could immensely enhance the CL of the reaction of cerium sulfate and tris(2,2‐bipyridyl) ruthenium (II) in acidic medium. Under optimal experimental conditions, CL intensity was favorably linear for OTCH in the range 5.0 × 10−7 to 5.0 × 10−5 g/ml, with a detection limit of 1.5 × 10−7 g/ml (S/N = 3). The relative standard detection was 4.76% for 5.0 × 10−6 g/ml (n = 11). This method was successfully applied to the analysis of OTCH in milk and egg white samples. According to the results of the kinetic curves for OTCH in the Ru(bipy)32+–Ce(SO4)2 CL system, together with CL and ultraviolet (UV)–visible spectra, the possible mechanism of the CL reaction is discussed briefly.

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Determination of sulfonamide antibiotics in wastewater: A comparison of solid phase microextraction and solid phase extraction methods

Cited by 189 publications

References 33 publications

An overview of analytical methodologies for the determination of antibiotics in environmental waters

An overview of analytical methodologies for the determination of antibiotics in environmental waters

Environmental Applications of Solid Phase Microextraction Techniques

Determination of oxytetracycline hydrochloride in milk and egg white samples using Ru(bipy)₃²⁺–Ce(SO₄)₂ chemiluminescence

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Determination of sulfonamide antibiotics in wastewater: A comparison of solid phase microextraction and solid phase extraction methods

Cited by 189 publications

References 33 publications

An overview of analytical methodologies for the determination of antibiotics in environmental waters

An overview of analytical methodologies for the determination of antibiotics in environmental waters

Environmental Applications of Solid Phase Microextraction Techniques

Determination of oxytetracycline hydrochloride in milk and egg white samples using Ru(bipy)32+–Ce(SO4)2 chemiluminescence

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Product

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Determination of oxytetracycline hydrochloride in milk and egg white samples using Ru(bipy)₃²⁺–Ce(SO₄)₂ chemiluminescence