Determination of the Influence of Multiple Closed Recycling Loops on the Property Profile of Different Polyolefins

Langwieser, Johanna; Schweighuber, Andrea; Felgel-Farnholz, Alexander; Marschik, Christian; Buchberger, Wolfgang; Fischer, Joerg

doi:10.3390/polym14122429

Cited by 9 publications

(5 citation statements)

References 20 publications

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“…Again, almost no standard deviations of the individual measurement points are visible. Langwieser et al [20] discussed the influence of multiple processing (e.g., plastics recycling) on various properties such as mechanical and thermal properties. In particular, the strain at break values decrease significantly with increased recycling loops.…”

Section: Modeling With Recyclate Blendsmentioning

confidence: 99%

“…PP is influenced by thermo-oxidative and UV light-initiated degradation in warm and bright environments leading to chain scission and thus to molar mass reduction and MFR increase [16]. This effect in combination with the influence of material changes on thermal and mechanical properties is already discussed in the literature by parametrization of different formulations [17][18][19][20][21][22][23]. Nevertheless, this paper discusses MFR value changes as they are of most importance for machine operators.…”

Section: Introductionmentioning

confidence: 99%

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Application of Mixing Rules for Adjusting the Flowability of Virgin and Post-Consumer Polypropylene as an Approach for Design from Recycling

Traxler¹,

Marschik²,

Farthofer

et al. 2022

Polymers

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To enable the use of recyclates in thermoformed polypropylene products with acceptable optical appearance and good mechanical stability, a multilayer structure of virgin and recycled material can be used. When producing multilayer films with more than two layers, the used materials should have similar melt flow properties to prevent processing instabilities. In the case of a three-layer film, post-consumer recyclates are often hidden in the core layer. Due to the inconsistent melt flow properties of post-consumer recyclates, the adjustment of the melt flow properties of the core layer to those of the outer layers has to be realized by blending with virgin materials. In order to understand the effect of mixing with a virgin material with a certain pre-defined melt flow rate (MFR), material mixtures with different mixing partners from various sources were realized in this study. Hence, the pre-defined virgin material was mixed with (i) virgin materials, (ii) artificial recyclates out of a mixture of different virgin materials, and (iii) commercially available recyclates. These blends with mixing partner contents ranging from 0–100% in 10% increments were prepared by compounding and the MFR of each mixture was determined. For a mathematical description of the mixing behavior and furthermore for a proper MFR prediction of the material mix, existing mixing rules were tested on the three pre-defined sample groups. Therefore, this paper shows the applicability of different mixing rules for the prediction of the MFR of material blends. Furthermore, a new mixing rule was developed using symbolic regression based on genetic programming, which proved to be the most accurate predictive model.

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Section: Modeling With Recyclate Blendsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Application of Mixing Rules for Adjusting the Flowability of Virgin and Post-Consumer Polypropylene as an Approach for Design from Recycling

Traxler¹,

Marschik²,

Farthofer

et al. 2022

Polymers

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“…Nevertheless, f-rPE_2 and f-rPE_3 only show a moderate substitution potential as the MFR falls short of the target values for blow-molding applications. This can potentially be caused by cross-linking of polymer chains, which is a potential mechanism in PE-HD degradation [34].…”

Section: Polyethylene Recyclatesmentioning

confidence: 99%

Polyolefin Recyclates for Rigid Packaging Applications: The Influence of Input Stream Composition on Recyclate Quality

2023

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In order to shift to a circular plastics economy, high quality recyclates are required to effectively substitute virgin materials. Current approaches to empirically quantify the substitutability for recyclates are mainly limited by the abundance of virgin material grades along with a lack of adequate application-specific property profiles. In contrast, this work aims for a holistic analysis of the substitution potential of polyolefin recyclates intended for rigid packaging applications. This approach is fundamentally based on the classification of virgin polyolefins into different application-specific sub-groups with defined property windows derived from supplier data sheets, which allows for a generalization within one polymer type without neglecting the various available material grades. Moreover, the findings should provide valuable information for improvements of quality-defining process steps along the value chain of mechanical recycling. Therefore, it is of great importance to correlate the input stream composition of the investigated recyclates with the obtained qualities. The investigation of the substitution potential for selected recyclates clearly highlights the necessity of functional recycling for enhanced quality levels, which especially affects the sorting step in the recycling value chain. This work illustrates that a homogeneous waste stream directly correlates with a high substitution potential. Thus, the development of economically viable sorting strategies which take the functionality of plastic waste products into account must be targeted in future research. Furthermore, the development of detailed application-specific property windows in a joint effort with manufacturers should be pursued, as it allows for a meaningful empirical quantification of the substitutability for recyclates obtained from mechanical recycling.

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“…Various studies in laboratory environments were already carried out to address this topic. The main results are an increasing MFR, a decreasing ductility, and a drop in the oxidation induction temperature, which corresponds to a decreased molecular weight [ 12 , 13 , 14 , 15 , 16 , 17 ].…”

Section: Introductionmentioning

confidence: 99%

Simultaneous Modification of Properties Relevant to the Processing and Application of Virgin and Post-Consumer Polypropylene

Traxler¹,

Kaineder

Fischer

2023

Polymers

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Post-consumer recyclates often have a property profile that results from mixing a variety of products, which are made from different materials, produced by different processing methods, and coming from applications with different lifetimes. This usually leads to a mixture of all these material properties in the recycling process. In contrast, virgin materials are specifically designed for applications and thus offer all the necessary properties for the intended products. In order to be able to use recycled materials for specific and demanding applications, not only the viscosity, which is important for processing and often varies greatly with recyclates, but also the mechanical properties, particularly the tensile modulus and impact strength, must be adjusted. For this purpose, various virgin materials of polypropylene homopolymers, random copolymers, and block copolymers with different flowabilities were mixed in different proportions and their properties were determined. The flowability of homopolymers and random copolymers in the blend behaved very similarly, while block copolymers exhibited a different behavior in some cases. By incorporating homopolymers into blends, the stiffness of the resulting material blend can be very well adjusted. The addition of random copolymers can increase strain at break, and the addition of block copolymers results in a significant increase in impact strength. In numbers, the maximum adjustment range for tensile modulus, yield stress, strain at break, and impact strength are 880 MPa, 14 MPa, 185%, and 6.9 kJ/m2, respectively. While a good and reliable prediction of property profile is possible for polymer blends with different virgin materials, the resulting material properties for polymer blends of virgin and recycled materials are also influenced by impurities. In this work, however, a good prediction was also achieved for recyclate blends.

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Determination of the Influence of Multiple Closed Recycling Loops on the Property Profile of Different Polyolefins

Cited by 9 publications

References 20 publications

Application of Mixing Rules for Adjusting the Flowability of Virgin and Post-Consumer Polypropylene as an Approach for Design from Recycling

Application of Mixing Rules for Adjusting the Flowability of Virgin and Post-Consumer Polypropylene as an Approach for Design from Recycling

Polyolefin Recyclates for Rigid Packaging Applications: The Influence of Input Stream Composition on Recyclate Quality

Simultaneous Modification of Properties Relevant to the Processing and Application of Virgin and Post-Consumer Polypropylene

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