Determination of total arsenic and toxicologically relevant arsenic species in fish by using electrothermal and hydride generation atomic absorption spectrometry

Serafimovski, Ivan; Karadjova, Irina; Stafilov, Trajče; Tsalev, Dimiter L.

doi:10.1016/j.microc.2006.01.021

Cited by 41 publications

(17 citation statements)

References 34 publications

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“…Dorm-1 and Tort-1 species have also been quantified and although only total As is certified in both materials, our species concentration are close to the reported in others works [50][51][52][53] . Our results were in mg g -1 , for Dorm-1: AB (15.0), and DMA (0.54), and the reported paper from others [50][51][52][53] are AB (15.5 -14.1) and DMA (0.60).…”

Section: Total As Contentsupporting

confidence: 89%

“…Our results were in mg g -1 , for Dorm-1: AB (15.0), and DMA (0.54), and the reported paper from others [50][51][52][53] are AB (15.5 -14.1) and DMA (0.60). For the Tort-1 material, we found AB (15.3), DMA (1.41) and As(V) (0.30) and AC (Nd), and the reported results were: AB (16.0) , DMA (1.64, and 1.01), AC ( 0.04), and As(V) (0.39) 57 -59 .…”

Section: Total As Contentsupporting

confidence: 85%

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TOTAL AND MAIN As SPECIES PRESENT IN CARDIOVASCULAR TISSUES OF PEOPLE LIVINGIN As CONTAMINATED AREAS

Pizarro

Roman-Silva

Solar³

et al. 2012

J. Chil. Chem. Soc.

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The concentration levels of As in the Chilean II Region of Antofagasta produces non cancer health outcomes such as cardiovascular diseases and in last term heart attack. On this study, the determination of total As content and main inorganic and organoarsenic species found in three heart tissues (auricle, mammary artery and fat) and the saphene vein of people living in the Chilean II Region, suffering coronary thrombosis has been carried out. Comparison with similar tissues of patients from other non-contaminated areas has been undertaken.The extraction of As species occurred in methanol: water (1:1) and As species determination have been used the tandem HPLC-ICP-MS using the Hamilton PRP X100 anion column. For total As determination has been performed by HG-AAS and ICP-MS.The auricle and in less extend the saphene support the higher As concentration (mean values of 7.7 and 2.5 µg g -1 , respectively), being As(III) the predominant species. Methylarsonate (MA) and dimethylarsinate (DMA) is not a favoured mechanism.The presence of high total As and high As(III) species content in the auricle and saphene of more contaminated people, the damage found in the saphene tissue and the global characteristics of the people under study in which the As stigmas are present in all of them, suggests that As could be involved in the cardiovascular diseases.

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Section: Total As Contentsupporting

confidence: 89%

Section: Total As Contentsupporting

confidence: 85%

TOTAL AND MAIN As SPECIES PRESENT IN CARDIOVASCULAR TISSUES OF PEOPLE LIVINGIN As CONTAMINATED AREAS

Pizarro

Roman-Silva

Solar³

et al. 2012

J. Chil. Chem. Soc.

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“…MWAE provides a technique whereby intact organic and organometallic compounds can be selectively extracted. Methods for the speciation of As [107,108] and Se [109] using MWAE are proposed in the literature. Most of them involve the use of HG coupled with AAS or ICP-MS, show adequate sensitivity and are fast and simple.…”

Section: Aqueous Samplesmentioning

confidence: 99%

Non-chromatographic atomic spectrometric methods in speciation analysis: A review

Vieira

Grinberg

Bobeda

et al. 2009

Spectrochimica Acta Part B: Atomic Spectroscopy

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“…[6][7][8] For determination and speciation of ultra trace concentrations of As in urine and whole blood samples an extraction procedure is necessary to get arsenic species in solution before analysis. Also, it requires sensitive analytical techniques such as; ion chromatography-inductively coupled plasma-mass spectrometry (IC-ICP-MS), high performance liquid chromatography coupled to inductively coupled plasma mass spectrometry (HPLC-ICP-MS), 9-11 coprecipitation, 12 inductively coupled plasma atomic emission spectrometry (ICP-AES), 13 HPLC coupled to inductively coupled plasma mass spectrometry, 14 hydride generation atomic absorption spectrometry (HGAAS), 15,16 hydride generation and atomic fluorescence spectrometry (HGAFS), 17,18 electrothermal atomic absorption spectrometry (ETAAS) 19 and chemiluminescence method 20 have been recommended for the purpose. Among them, HGAAS is probably the most common technique used for low level concentrations of As in biological samples, due to its high sensitivity, speed of analysis and minimum sample preparation.…”

Section: Introductionmentioning

confidence: 99%

Ultra-trace Arsenic Determination in Urine and Whole Blood Samples by Flow Injection-Hydride Generation Atomic Absorption Spectrometry after Preconcentration and Speciation Based on Dispersive Liquid-Liquid Microextraction

Shirkhanloo¹,

Rouhollahi

Mousavi³

2011

Bulletin of the Korean Chemical Society

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A noble method for pre-concentration and speciation of ultra trace As (III) and As (V) in urine and whole blood samples based on dispersive liquid-liquid microextraction (DLLME) has been developed. In this method, As (III) was complexed with ammonium pyrrolidine dithiocarbamate at pH = 4 and Then, As (III) was extracted into the ionic liquid (IL). Finally, As (III) was back-extracted from the IL with hydrochloric acid (HCl) and its concentration was determined by flow injection coupled with hydride generation atomic absorption spectrometry (FI-HGAAS). Total amount of arsenic was determined by reducing As (V) to As (III) with potassium iodide (KI) and ascorbic acid in HCl solution and then, As (V) was calculated by the subtracting the total arsenic and As (III) content. Under the optimum conditions, for 5-15 mL of blood and urine samples, the detection limit (3σ) and linear range were achieved 5 ng L −1 and 0.02-10 μg L −1, respectively. The method was applied successfully to the speciation and determination of As (III) and As (V) in biological samples of multiple sclerosis patients with suitable precision results (RSD < 5%). Validation of the methodology was performed by the standard reference material (CRM).

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Determination of total arsenic and toxicologically relevant arsenic species in fish by using electrothermal and hydride generation atomic absorption spectrometry

Cited by 41 publications

References 34 publications

TOTAL AND MAIN As SPECIES PRESENT IN CARDIOVASCULAR TISSUES OF PEOPLE LIVINGIN As CONTAMINATED AREAS

TOTAL AND MAIN As SPECIES PRESENT IN CARDIOVASCULAR TISSUES OF PEOPLE LIVINGIN As CONTAMINATED AREAS

Non-chromatographic atomic spectrometric methods in speciation analysis: A review

Ultra-trace Arsenic Determination in Urine and Whole Blood Samples by Flow Injection-Hydride Generation Atomic Absorption Spectrometry after Preconcentration and Speciation Based on Dispersive Liquid-Liquid Microextraction

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