Determination of trace phenolic acids in fruit juice samples using multiple monolithic fiber solid-phase microextraction coupled with high-performance liquid chromatography

Abstract

A simple and sensitive analytical approach of MMF/SPME-LD-HPLC/DAD was proposed for the determination of trace level of phenolic acids in fruit juice samples.

Development of magnetism‐assisted in‐tube solid phase microextraction of phenolic acids in fruit juices prior to high‐performance liquid chromatography quantification

“…To further illustrate the features of current method in the analysis of PAs in fruit juices, a comparison with previously reported ABE-based approaches for the determination of PAs was performed. As summarized in Supporting Information Table 2, our method used the lowest amount of sample [16,[29][30][31][32][33][34][35][36]. The consumption of extraction solvent in the current method was less than SPE-HPLC/DAD [29], pipette-tip (PT) SPE-HPLC/UV [31], SPME-GC/MS [33], poly (vinylimidazole-ethylene dimethacrylate) monolith (VIED)-based MMF-SPME (VIED/MMF-SPME)-HPLC/DAD [16], molecularly imprinted polymer (MIP)based MMF-SPME (MIP/MMF-SPME)-HPLC/DAD [34], and bar adsorptive microextraction (BAμE)-CE/DAD [36].…”

“…However, the complexity of sample matrices, low contents, and high polarity of PAs require appropriate sample preparation procedure prior to chromatographic analysis. Heretofore, solvent-based extraction [11,12] and adsorbent-based extraction (ABE) [13][14][15][16][17][18][19] have been employed to capture PAs in various complex samples. Due to using less toxic solvent, ABE is more appealing than solvent-based extraction.…”

“…Due to using less toxic solvent, ABE is more appealing than solvent-based extraction. SPE [13,14], SPME [15], multiple monolithic fiber SPME (MMF-SPME) [16], magnetic SPE [17,18], and stir bar sorptive extraction [19] belong to ABE technologies and they have displayed satisfying pre-concentrated performance for PAs. However, these technologies still encounter some dilemmas such as poor stability of extraction media, necessary of multi-step extraction processes, difficulty in the preparation of extraction media, and low extraction efficiency.…”

Fruit‐based juices: Focus on antioxidant properties—Study approach and update

“…Recently, Shah, Rahman, Shamsuddin, and Adzahan () described hydroxycinnamic acid profile (chlorogenic acid, caffeic acid, and coumaric acid) as well as flavanones (naringin, hesperidin, and narirutin) in Malaysian variety of Pummelo ( Citrus grandis L. Osbeck). Recently, Pei and Huang () have proposed a new method to determine traces of phenolic acids (p‐hydroxybenzoic acid, syringic acid, p‐coumaric acid, and ferulic acid) in fruit juice samples by using multiple monolithic fiber solid‐phase microextraction coupled with high‐performance liquid chromatography.…”

“…Generally, the phenolic acids present in foodstuffs are originated from two phenolic compounds: benzoic and cinnamic acids. Gallic, phydroxybenzoic, vanillic, and syringic acids ( Recently, Pei and Huang (2016) have proposed a new method to determine traces of phenolic acids (p-hydroxybenzoic acid, syringic acid, p-coumaric acid, and ferulic acid) in fruit juice samples by using multiple monolithic fiber solid-phase microextraction coupled with high-performance liquid chromatography.…”