a b s t r a c tA dynamic model of a discrete reversible fuel cell (RFC) system has been developed in a Matlab Simulink ® environment. The model incorporates first principles dynamic component models of a proton exchange membrane (PEM) fuel cell, a PEM electrolyzer, a metal hydride hydrogen storage tank, and a cooling system radiator, as well as empirical models of balance of plant components. Dynamic simulations show unique charging and discharging control issues and highlight factors contributing to overall system efficiency.© 2008 Elsevier B.V. All rights reserved.
Background and introductionReversible fuel cell (RFC) systems act as "rechargeable" energy storage devices designed to work as turn-key systems with electricity being the only input and output. This may allow future systems to replace traditional chemical storage batteries in applications where the potential performance benefits outweigh the cost tradeoffs [1]. The major components in an RFC system are a fuel cell, an electrolyzer (unitized RFC systems use just one device to perform both functions, discrete systems have separate fuel cell and electrolyzer devices), and a hydrogen storage tank. Numerous balance of plant components are also necessary for a practical system [2]. It is only through thorough modeling of all these components that true system efficiencies can be estimated. Fig. 1 shows a schematic diagram of the RFC system modeled in this work, demonstrating the complex auxiliary components and circuitous integration of all of the parts.The RFC system is "charged" by supplying electricity to an electrolyzer that disassociates water yielding hydrogen and oxygen. The oxygen is vented to the atmosphere and the hydrogen is stored in the hydrogen tank. The current system uses a reversible metal hydride compound confined in an aluminum tank for hydrogen storage. When power is needed from the system, hydrogen is supplied by the tank to the fuel cell where it is combined with air to produce electricity, heat, and water. * Corresponding author. Tel.: +1 949 824 1999; fax: +1 949 824 7423.
E-mail address: jb@nfcrc.uci.edu (J. Brouwer).The RFC energy storage system is unique when compared to traditional chemical batteries because the power capability, energy storage capacity, and recharge rate are all determined independently [3]. With the exception of shared controls and plumbing, the hydrogen tank capacity solely determines the energy storage of the system, the fuel cell power output governs the power output of the system, and the electrolyzer power determines the "recharge" rate of the system. These properties lead to system advantages in specialized applications, particularly for those applications that require low to moderate power, long duration performance, and/or strict weight requirements. The fuel cell and electrolyzer can be sized as needed for the power requirement, while the hydrogen storage tank can simply be sized up or down, independently, to meet the energy storage requirement. A traditional chemical battery would require increases i...