Development of Methodologies for Different Degrees of Resolution of Linear Alkylbenzene Sulfonates in Groundwater and Wastewater by Liquid Chromatography Using Sodium Dodecyl Sulphate

Olmo, M. del; Garballo, Antonio; Nimer, M.; López, Ignacio; Ferrer, J.; Vı́lchez, J.L.

doi:10.1365/s10337-004-0352-3

Cited by 5 publications

(5 citation statements)

References 11 publications

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“…We confirmed, using the method proposed by Del Olmo et al (2004), that the level of LAS in this water was minor according to the limit of detection found (21 ng ml À1 ). The validation samples were prepared using 100 ml of this water spiked with SPC at the same concentration levels as the standards used for calibration and treated as these standards, according to the procedure described.…”

Section: Validation and Application Of The Methodssupporting

confidence: 78%

“…Also, during the biodegradation study we also determined total LAS in the groundwater samples using the method proposed by Del Olmo et al (2004). The obtained results, summarized in Table 4, show that LAS are biodegraded during the lixiviation process, and we found levels of different metabolites (SPC) in the groundwater samples collected into the hydro-captors.…”

Section: Validation and Application Of The Methodsmentioning

confidence: 84%

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Determination of Sulfophenyl Carboxylic Acids in Agricultural Groundwater Samples by Liquid Chromatography with Fluorescence Detection

et al. 2008

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We have developed an analytical method to determine six sulfophenyl carboxylic acids (SPC) in agricultural groundwater samples. It involves a solidphase extraction (SPE) procedure and subsequent separation and determination using liquid chromatography with fluorescence detection (LC-FD).The quantification limits ranged between 0.7 and 1.2 ng ml À1 . The proposed method was proved satisfactorily for the detection and determination of these compounds in groundwater samples during a study into the biodegradation of linear alkylbenzene sulfonates (LAS) in an agricultural soil sampled from the irrigated plain to the west of Granada (Spain).

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Section: Validation and Application Of The Methodssupporting

confidence: 78%

Section: Validation and Application Of The Methodsmentioning

confidence: 84%

Determination of Sulfophenyl Carboxylic Acids in Agricultural Groundwater Samples by Liquid Chromatography with Fluorescence Detection

et al. 2008

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“…This water was free of LAS, as confirmed by analysis [33]. The usual precautions were taken to avoid contamination.…”

Section: Validation and Application Of The Methodsmentioning

confidence: 82%

“…Also, during the biodegradation study, the determination of total LAS in the groundwater samples was made using the method proposed by Del Olmo et al [33].…”

Section: Validation and Application Of The Methodsmentioning

confidence: 99%

Determination of sulfophenyl carboxylic acids in agricultural groundwater samples by CE with ultraviolet absorption detection

et al. 2008

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An analytical method for the determination of six sulfophenyl carboxylic acids, namely (p-sulfophenyl)acetic, 2-(p-sulfophenyl)propionic, 2-(p-sulfophenyl)butyric, 3-(p-sulfophenyl)butyric, 4-(p-sulfophenyl)butyric, and 5-(p-sulfophenyl)valerianic acid, in agricultural irrigation water samples was developed. It involves an SPE procedure, an on-line preconcentration normal stacking mode and subsequent separation and determination using CE with UV detection (CE-UV). p-Sulfobenzoic acid was used as internal standard. The compounds were separated with an uncoated capillary and a 25 mM ammonium acetate/acetic acid buffer solution (pH 5.5) with 2-propanol (30% v/v) and 0.75 mM CTAB. Analyses were run at -25 kV, 25 degrees C, and 100 s of hydrodynamic injection with UV detection at 225 nm. Quantification limits found ranged between 4 and 6 ng/mL. The proposed method was validated using a recovery assay. It was satisfactorily used for the determination of these compounds in groundwater samples to track down the biodegradation of linear alkylbenzene sulfonates in an agricultural soil from the fertile plain of Granada (Spain).

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“…Reversed-phase high performance liquid chromatography (RP-HPLC) with a C 18 or C 8 column (Wangkarn et al, 2005;Lunar et al, 2006) provides a good separation of LAS mixtures. It has been reported that the short hydrophobic chain homologues C 10 -C 13 LAS could be separate easily under appropriate mobile phase (CH 3 OH/H 2 O or CH 3 CN/H 2 O), and the separation of isomers of C 10 -C 13 LAS also has been done (Akyuz and Roberts, 2002;del Olmo et al, 2004). In this work, a sample of HABS that was from Daqing Oil Refinery has been studied on its composition and interfacial activities.…”

Section: Introductionmentioning

confidence: 99%

The Composition and Interfacial Activity of Alkyl Benzene Sulfonates Used in Oil Recovery

Wang

Zhang

et al. 2015

Petroleum Science and Technology

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The composition of heavy alkyl benzene sulfonates (HABS) was determined and the HABS was separated by a preparative HPLC. The surface and interfacial tensions of the components were measured. The results show that the HABS is a mixture of homologues, C n ABS, with different alkyl carbon numbers ranging from 12 to 25 on phenyl group. The CMC of six components, C 12 ABS, C 13 ABS, C 16 ABS, C 17 ABS, C 18 ABS, and C 19 ABS are 0.401-0.030 g·L −1 . The C 16 ABS has the strongest interfacial activities. There occurred synergism between C 16 ABS and ionized organic acids in the crude oil produced by Na 2 CO 3 .

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Development of Methodologies for Different Degrees of Resolution of Linear Alkylbenzene Sulfonates in Groundwater and Wastewater by Liquid Chromatography Using Sodium Dodecyl Sulphate

Cited by 5 publications

References 11 publications

Determination of Sulfophenyl Carboxylic Acids in Agricultural Groundwater Samples by Liquid Chromatography with Fluorescence Detection

Determination of Sulfophenyl Carboxylic Acids in Agricultural Groundwater Samples by Liquid Chromatography with Fluorescence Detection

Determination of sulfophenyl carboxylic acids in agricultural groundwater samples by CE with ultraviolet absorption detection

The Composition and Interfacial Activity of Alkyl Benzene Sulfonates Used in Oil Recovery

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