Abstract. The photorecombination spectrum of 48 Ti 18+ was measured employing the merged electron-ion beams technique at a heavy-ion storage ring. The experimental electron-ion collision energy range 0−80 eV comprises all dielectronic recombination (DR) resonances associated with 2s → 2p (∆N = 0) core excitations as well as trielectronic recombination (TR) resonances that involve 2s 2 → 2p 2 core double-excitations. At low collision energies DR resonances are observed that are associated with the excitation of metastable 2s 2p 3 P0 primary ions with nearly infinite lifetime for the isotope 48 Ti with zero nuclear spin. For the isotope 47 Ti with nonzero nuclear spin hyperfine quenching of these resonances occurs. The procedure for obtaining the associated time constant from a recombination measurement is outlined.
IntroductionThe ns np 3 P 0 state in divalent atoms and ions is the first excited state above the ns 2 1 S 0 ground state. Its decay by a one-photon J = 0 → J = 0 transition is strictly forbidden and the lifetime of the 3 P 0 state is nearly infinite provided the ion has zero nuclear spin (I = 0). If I > 0 the hyperfine interaction mixes levels with different J and, consequently, the 3 P 0 level acquires a finite lifetime. This hyperfine quenching has been treated theoretically for Be-like, Mg-like and Zn-like ions [1,2,3,4]. Theoretical work on neutral alkaline-earth-metal atoms [5,6] was motivated by the idea to use the hyperfine induced 3 P 0 → 1 S 0 transition in ultraprecise atomic clocks. In another application the 13 C 2+ ( 3 P 0 → 1 S 0 ) fluorescence from planetary nebulae was measured to infer the 13 C/ 12 C abundance ratio and, thereby, to gain insight into stellar nucleosynthesis [7].So far, the only experimental values for ns np 3 P 0 → ns 2 1 S 0 hyperfine induced (HFI) transition rates were obtained for In + (n=5) [8] stored in a radio frequency trap and for Be-like N 3+ from astrophysical observations [9]. Although the latter result had a rather large uncertainty of ±33%, it allows one to discriminate between the two theoretical values [1,3] that are available for this ion and that differ by almost a factor of 4. In view of these theoretical uncertainties it is evident that accurate experimental benchmarks are highly desirable, especially for few electron systems such as Be-like ions where correlation effects are particularly strong.In the present work the hyperfine quenching of the 2s 2p 3 P 0 state of Be-like 47 Ti 18+ was observed in dielectronic recombination (DR) experiments carried out at the heavy-ion