Antiferromagnetic (AFM) skyrmions are envisioned as ideal localized topological magnetic bits in future information technologies. In contrast to ferromagnetic (FM) skyrmions, they are immune to the skyrmion Hall effect 1, 2 , might offer potential terahertz dynamics 3, 4 while being insensitive to external magnetic fields and dipolar interactions. Although observed in synthetic AFM structures 5 and as complex meronic textures in intrinsic AFM bulk materials 6, 7 , their realization in non-synthetic AFM films, of crucial importance in racetrack concepts, has been elusive. Here, we unveil their presence in a row-wise AFM Cr film deposited on PdFe bilayer grown on fcc Ir(111) surface. Using first principles, we demonstrate the emergence of single and strikingly interpenetrating catenated AFM skyrmions, which