Marine submersible buoy systems are widely-used equipment for ocean resource development. The marine submersible buoy system studied in this paper consists of the submersible buoy, the battery compartment, the anchor block, the mooring line, and the power supply cable. To study the mechanical behavior and obtain the speed variation of each component during the anchor last deployment, this paper establishes the free surface computational fluid dynamics model of marine submersible buoy systems based on the VOF method. This model includes the incompressible Navier–Stokes equations, the Renormalization-Group turbulence model, and the fractional areas/volume obstacle representation method. The free fluid surface is tracked using the VOF method. The lumped mass method is used to simulate the mooring line and power supply cable. The results showed that the tension forces increase when the mooring lines were straightened. Subsequently, the tension forces gradually decrease with oscillations. After the anchor block sinks to the sea floor, the positive buoyancy of the battery compartment and the buoy will cause large tension on the mooring line and power supply cable.