Low-cost thin film modules based on copper antimony tin sulphide (CATS) were introduced for solar harvesting to compete for the already developed compound semiconductors. In this study, CATS thin films were deposited on soda lime glass using thermal evaporation technique followed by a rapid thermal annealing in an argon atmosphere. X-ray diffraction analysis revealed that the annealed samples were poly-crystalline and their crystallinity was improved with increasing annealing temperature. The constituent elements and their corresponding chemical states were identified using X-ray photoelectron spectroscopy. The obtained optical band gap for CATS thin film was found 1.58±0.06 eV which is nearly equal the optimal band gap value of CIGS and CdTe and GaAs -one of the highly efficient thin film material for solar cell technology. Furthermore, the good optical absorbance and low transmittance of the annealed CATS thin films in the visible region of light spectrum assured the suitability of the CATS thin films for solar cell applications.