2015
DOI: 10.3866/pku.whxb201507291
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Effect of Cu Loading on the Structure and Catalytic Performance of the LNT Catalyst CuO-K<sub>2</sub>CO<sub>3</sub>/TiO<sub>2</sub>

Abstract: 摘要: 采用连续浸渍法制备了一系列非贵金属稀燃NO x 阱(LNT)催化剂CuO-K 2 CO 3 /TiO 2 , 考察了Cu负载量对EXAFS), 氢气程序升温还原(H 2 -TPR)和原位漫反射红外光谱(in-situ DRIFTS)等技术详细表征了催化剂的结 构. 结果表明, 不同Cu负载量的催化剂中, 铜物种均主要以CuO相存在. 铜的负载量直接影响铜物种、钾物种 的存在状态, 高分散的CuO相与表面K 2 CO 3 之间存在较强相互作用, 这种相互作用不仅有利于NO x 的储存, 而 且有利于增强催化剂的稳定性. in-situ DRIFTS结果表明, NO x 储存过程中产生的两个负峰(1436和1563 cm -1 )缘于碳酸盐的分解, 这间接证明了碳酸盐作为储存介质参与到NO x 储存反应中. EXAFS结果表明, 经过 15个稀燃/富燃循环测试, 催化剂中的CuO相仍保持稳定. 基于以上表征结果, 提出了CuO和K 2 CO 3 在催化剂表 面的分布模型, 并探讨了NO x 储存还原的可能机理.

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(1 citation statement)
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“…The total electronic transportation cannot be explained with the hopping conduction in this region while it is more dominated at the medium and high electrical fields. [44,45] Besides, the leakage current can be relatively larger due to the higher defect density. For the nonlinear leakage conduction mechanisms, several kinds of theorems including Schottky emission, [46] Poole-Frenkel emission, [47] Fowler-Nordheim tunneling, [48] and Space-charge-limited-current (SCLC) [49] have been proposed.…”
Section: Resultsmentioning
confidence: 99%
“…The total electronic transportation cannot be explained with the hopping conduction in this region while it is more dominated at the medium and high electrical fields. [44,45] Besides, the leakage current can be relatively larger due to the higher defect density. For the nonlinear leakage conduction mechanisms, several kinds of theorems including Schottky emission, [46] Poole-Frenkel emission, [47] Fowler-Nordheim tunneling, [48] and Space-charge-limited-current (SCLC) [49] have been proposed.…”
Section: Resultsmentioning
confidence: 99%