In order to efficaciously harvest these mechanical/bio-mechanical energies, piezoelectric and triboelectric nanogenerators (PENGs and TENGs) are frequently utilized owing to their admirable energy harvesting behaviour. Aside from PENGs, TENGs show a great potential in various applications like pressure, motion, and tactile sensors. [1][2][3][4] The principle of TENGs is based on electrostatic induction and contact electrification where by using frictional force electric charges are generated. The advantage of using TENGs is for its high output power density, high durability, wide choice of materials, and simple design. The contactseparation mode, lateral-sliding and freestanding mode are very well known techniques for enhancement of the TENG output performance. [5][6][7] Among these, contactseparation mode is more efficient for its easy fabrication and good output performance. [8,9] On the other hand in case of PENG the stacked layers don't come in contact with each other and thus, there is no friction between these layers, because the piezoelectric material or composite is stacked between two electrodes. Therefore PENGs are appropriate for powering biomedical devices, [10] micro/nano systems, [11] and wearable electronic devices. [12,13] Thus, from small-scale to large-scale applications, it is very useful to fabricate a device that shows multifunctional mechanism, i.e., piezoelectric as well as triboelectric mechanism for better result. [14] The fabrication of PENGs can be done with different kinds of materials like lead zirconate titanate (PZT), [15] ZnO, [16] BaTiO 3 , [17] and GaN [18] for their good piezoelectric properties. For the enchanting features and different types of potential applications, the twodimensional (2D) layered transition metal dichalcogenides (TMDs) attract a huge attention nowadays. [19,20] Molybdenum disulfide (MoS 2 ) is one such kind of TMDs that has superior, distinctive functional properties that includes high current-carrying capacity and large carrier mobility that come out with emerging applications. [21] MoS 2 has very interesting structure, with different crystal phases such as 1-layer hexagonal unit cell (1H), 2-layer hexagonal crystal cell (2H), and three-layer rhombohedral unit cell (3R). The monolayer MoS 2 (1H) has a fascinating property that can demonstrate piezoelectricity with piezoelectric coefficient (2.99 p.m. V À1 ) to in-plane d11. [22] With increasing the number of odd layer of MoS 2 , its piezoelectricity gradually decreases. [23] The noncentrosymmetric materials are very crucial for creating the mechanical stress that causes the dipole