Radon is a naturally occurring radioactive gas formed by the decay of uranium and thorium in the Earth's crust. At atomic number 86, it is the heaviest member of the noble or inert gas family, which also includes helium, neon, argon, krypton, and xenon. Unlike the other members of the family, radon has no stable isotopes. Of the 34 known radioactive isotopes of radon, only three are supported by the decay of primordial radionuclides, and only two occur with any significant abundance in nature. The three isotopes, along with their half‐lives, are
222
Rn (3.8235 days),
220
Rn (55.6 s), and
219
Rn (3.96 s). Both
222
Rn and
220
Rn decay by the emission of α‐particles and give rise to a number of short‐lived progeny.
222
Rn and
220
Rn are the only ones regarded as having any health impacts and this is due to their short‐lived progeny—
218
Po,
214
Pb,
214
Bi, and
214
Po from
222
Rn;
216
Po,
212
Pb,
212
Bi,
212
Po, and
208
Tl from
220
Rn. Being a gas, radon diffuses readily into the atmosphere and may build up to hazardous concentrations in confined spaces in homes and underground mines. Radon is the largest single contributor to natural background radiation exposure worldwide. Radon is now recognized as the second leading cause of lung cancer, following tobacco smoking, and is responsible for up to 20 000 deaths per year in the United States and 1900 deaths per year in Canada. Many countries have now established programs to reduce radon exposures to the population.