Effective passivation of black phosphorus transistor against ambient degradation by an ultra-thin tin oxide film

Wu, Dazhou; Peng, Zhijian; Jin, Chuanhong; Zhang, Zhiyong

doi:10.1016/j.scib.2019.04.021

Cited by 14 publications

(8 citation statements)

References 34 publications

(51 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

“…These works focused on the air-induced degradation of black phosphorus have motivated works to find effective methods to encapsulate black phosphorus at the early stages of isolation/fabrication to increase its longevity (25,26,38). Several encapsulation techniques have been reported to date including polymer dielectrics (10,39), atomic layer deposited (ALD) oxides (25,26,(40)(41)(42), hybrid metal organic chemical vapor deposition (MOCVD)/ALD coating of BN/Al 2 O 3 (43), electronbeam evaporated metallic thin films oxidized under ambient air (44), van der Waals heterostructures using boron nitride, MoS 2 and graphene flakes (7-9, 38, 45-48), and chemical functionalization (49)(50)(51)(52). In two different works, a thin native oxide layer on top of the black phosphorus surface has been formed by oxygen plasma (53) or thermal annealing etching (54).…”

Section: Passivation Methods: Encapsulation and Functionalizationmentioning

confidence: 99%

Degradation of Black Phosphorus upon Environmental Exposure and Encapsulation Strategies To Prevent It

Ryu

Castellanos-Gómez

Frisenda

2019

ACS Symposium Series

View full text Add to dashboard Cite

show abstract

Section: Passivation Methods: Encapsulation and Functionalizationmentioning

confidence: 99%

Degradation of Black Phosphorus upon Environmental Exposure and Encapsulation Strategies To Prevent It

Ryu

Castellanos-Gómez

Frisenda

2019

ACS Symposium Series

View full text Add to dashboard Cite

show abstract

“…The passivation scheme is to cover the BP surface with a stable oxide layer, which mainly consists of P 2 O 5 , [66]. Reprinted from [68], Copyright (2019), with permission from Elsevier. Reprinted with permission from [66].…”

Section: Passivation Coating Treatmentsmentioning

confidence: 99%

“…Copyright (2020) American Chemical Society. A1 2 O 3 , HfO 2 , MgO, SnO 2 , and ZnO in the ambient environment [64][65][66][67][68][69][70][71]. P 2 O 5 can also exist stably in an arid environment, which protects BP against the degradation.…”

Section: Passivation Coating Treatmentsmentioning

confidence: 99%

Recent progress on degradation mechanism and antioxidation of low-dimensional black phosphorus

Fu,

Li,

Yang

et al. 2024

2D Mater.

View full text Add to dashboard Cite

Among the allotropes of phosphorus, black phosphorus (BP) is one of the most thermodynamically stable structures. Due to its unique physical and chemical properties, BP has shown considerable potential in many applications, such as field-effect transistors, energy storage and conversion, and photocatalysis. However, low-dimensional BP is easily corroded by oxygen and water owing to the large specific surface area and unbonded lone pair electrons on the surface, which reduces its chemical stability in the environment. As a result, different passivation approaches, relying on noncovalent bonding, covalent functionalization, and surface coordination, are employed to enhance the stability and performance of BP. In this review, the degradation mechanisms of BP are first analyzed for the material in both its ground state and excited state. Subsequently, the promising strategies for improving stability are overviewed. A comprehensive and in-depth understanding of the oxidation mechanisms and protection strategies of BP will provide guidance for the large-scale applications of BP and its derivatives.

show abstract

“…Many researchers have proposed strategies for BP nanosheets, such as passivation layer protection, − organic compound modification, , metal nanoparticle decoration, − and encapsulation methods. , However, the stability of BPQDs has received less attention. Shao et al used PLGA shells to encapsulate BPQD cores, thus preventing the rapid degradation of BPQDs and significantly improving their photothermal performance in physiological environments.…”

Section: Introductionmentioning

confidence: 99%

Black Phosphorus Quantum Dots with a Core–Shell Nanostructure as a Water-Based Lubrication Additive

Dong

Wang

Gao

et al. 2023

ACS Appl. Nano Mater.

View full text Add to dashboard Cite

The unique tribological characteristics of black phosphorus quantum dots (BPQDs) have recently attracted much attention. However, the long-term stable lubrication of BPQDs and prevention of degradation in ultrapure water remain huge challenges. Herein, BPQDs@silica (BPQDs@SiO2) core–shell materials were designed and synthesized. The BPQDs are uniformly distributed in the SiO2 shell. The as-prepared BPQDs@SiO2 as the water-based lubrication additive has remarkable lubricity, wettability, and stability. In particular, compared with the average coefficient of friction (COF) and wear rate of ultrapure water, those of BPQDs@SiO2, being a water-based lubrication additive, could be reduced by 45.7 and 83.0% at 10 N and 150 r/min, respectively. The lubrication mechanisms of BPQDs@SiO2 as a water-based lubrication additive were proposed based on the friction test and wear surface analysis. The excellent lubricity performances of BPQDs@SiO2 are owed to the polishing of the SiO2 shell, the extreme pressure property of the BPQD core, and the tribo-chemical reaction film. This investigation established a simple, convenient, and feasible method for using the BPQDs@SiO2 materials as a water-based lubrication additive. It is expected that BPQDs with a core-shell nanostructure will open up new ideas for the development of excellent lubricating nanomaterials.

show abstract

Effective passivation of black phosphorus transistor against ambient degradation by an ultra-thin tin oxide film

Cited by 14 publications

References 34 publications

Degradation of Black Phosphorus upon Environmental Exposure and Encapsulation Strategies To Prevent It

Degradation of Black Phosphorus upon Environmental Exposure and Encapsulation Strategies To Prevent It

Recent progress on degradation mechanism and antioxidation of low-dimensional black phosphorus

Black Phosphorus Quantum Dots with a Core–Shell Nanostructure as a Water-Based Lubrication Additive

Contact Info

Product

Resources

About