Abstract. Recent technological advances have demonstrated the
feasibility of deploying spaceborne optical detectors with full polarimetric
capabilities. The measurement of all four Stokes coefficients opens
significant new opportunities for atmospheric aerosol studies and
applications. While considerable amounts of attention have been dedicated to
sensors with sensitivity to the total intensity and linear polarization
(represented by Stokes coefficients I, U, Q), there has been less attention
to the additional information brought by measuring circular polarization
(coefficient V). This report fills this gap in knowledge by providing an
overview of aerosol sources of circular polarization in the atmosphere and
discusses possible remote sensing signatures. In this paper, circularly polarized radiation that results from the
interaction of incident unpolarized radiation is considered in three
physical settings: optical activity originating in biogenic aerosols,
alignment of non-spherical particles in the presence of electrical fields
(such as dust, smoke, and volcanic ash), and aerosol multiple scattering
effects. Observational and theoretical evidence of, and the settings and
conditions for, non-zero aerosol circular polarization generated from
incident unpolarized radiation are here gathered and discussed. In addition,
novel radiative transfer simulations are shown to illustrate notable
spectral and other features where circular polarization may provide
additional information that is possibly independent from total intensity and
linear polarization-only observations. Current techniques for the detection of aerosol composition (also referred as
aerosol type) from space provide limited information. Remote identification
of aerosols such as smoke, volcanic ash, and dust particles can only be
accomplished with some degree of confidence for moderate to high
concentrations. When the same aerosols are found at lower concentrations
(but still high enough to be of importance for air quality and cloud
formation), these methods often produce ambiguous results. The circular
polarization of aerosols is rarely utilized, and we explore its value for
improved determination aerosol composition. This study is presented as an
overview with a goal to provide a new perspective on an overlooked optical
property and to trigger interest in further exploration of this subject.