Effects of pore structure and surface chemical characteristics on the adsorption of organic vapors on titanate nanotubes

Abstract

Effects of pore structure and surface chemical characteristics of titanate nanotubes (TNTs) on their adsorptive removal of organic vapors were investigated. TNTs were prepared via a hydrothermal treatment of TiO 2 powders in a 10 M NaOH solution at 150°C for 24 h, and subsequently washed with HCl aqueous solution of different concentrations. Effects of acid washing process (or the sodium content) on the microstructures and surface chemical characteristics of TNTs were characterized with nitrogen adsorption-desorption isotherms, FTIR, and water vapor adsorption isotherms. For the adsorption experiments, gravimetric techniques were employed to determine the adsorption capacities of TNTs for four organic vapors with similar heats of vaporization (i.e., comparable heats of adsorption) but varying dipole moments and structures, including n-hexane, cyclohexane, toluene, and methyl ethyl ketone (MEK), at isothermal conditions of 20 and 25°C. The experimental data were correlated by well-known vapor phase models including BET and GAB models. Isosteric heats of adsorption were calculated and heat curves were established. Equilibrium isotherms of organic vapors on TNTs were type II, characterizing vapor condensation to form multilayers. The specific surface area (and pore volume) and hydrophilicity of TNTs were the dominating factors for the determination of their organic vapors adsorption capacity. The GAB isotherm equation fitted the experimental data more closely than the BET equation. The heats of adsorption showed that the adsorption of organic vapors on TNTs was primarily due to physical forces and adsorbates with larger polarity might induce a stronger interaction with TNTs.

Competitive adsorption and selectivity of benzene and water vapor on the microporous metal organic frameworks (HKUST-1)

“…6). This is further evidence that the HKUST-1 possesses a highly energetic heterogeneity for water vapor adsorption [38].…”

Synthesis and Applications of Molecularly Imprinted Polymers Modified TiO2 Nanomaterials: A Review

“…In 1972, Japanese scholars Fujishima and Honda reported the results of research using hydrogen peroxide to decompose water with TiO 2 under UV light irradiation [72], the application of semiconductor materials in photocatalytic degradation has been further studied [73]. TiO 2 has been widely used in the photocatalytic degradation of environmental pollutants due to its suitable electronic band structure [74], biological and chemical inertness [75], strong oxidizing capability, light stability and non-toxicity, which make it to be one of the most promising photocatalyst one [76,77,78]. However, TiO 2 shows poor photocatalytic selectivity because photocatalytic reactions based on TiO 2 are accompanied by the formation of highly reactive ·OH radicals which are typically nonselective [79].…”

Layered titanate nanostructures: perspectives for industrial exploitation

“…The BET specific surface area of titanate nanotubes is between 200-300 m 2 • g −1 when calculated from the most common nitrogen adsorption isotherm. It is also possible to estimate the surface area from water adsorption isotherms evaluated by the Guggenheim-Anderson-de Boer (GAB) equation [58], but this method tends to overestimate the surface (approximately 350 m 2 • g −1 ) because water adsorption is significantly more complex on the hydrophilic titanate surface than nitrogen sorption [59]. Surface area values calculated from geometrical models are closer to the BET than to the GAB values.…”