“…Rare‐earth (RE) oxide films possess properties such as high mechanical durability, thermal stability, radiation resistance, high dielectric constant ( ε = 14−30) and very small leakage current density, refractive indexes of about 2, high transparency over a wide spectral range (between 0.22 and 2 µm), and variable electrical conductivity in different gaseous fluids. These properties justify their application as insulators in microelectronics, having a number of advantages over silica, HfO 2 , and ZrO 2 , as gas detectors, as luminophores, and in optical electronics . Tb is one of the RE metals, possesses an oxidation number from +3 to +4, and forms oxides according to the general formula R n O 2 n ‐2 m (R = Ce, Pr, Tb), depending on the procedure conditions .…”