2015
DOI: 10.1016/j.molcatb.2015.07.003
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Efficient hydroxylation of functionalized steroids by Colletotrichum lini ST-1

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Cited by 18 publications
(3 citation statements)
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“…Its 11α hydroxylation is a key step in synthesising prednisone and prednisolone or dexamethasone, and Rhizopus nigricans is the most widely used microorganism for industry purposes [48]. Other possible hydroxylation positions of this compound are 8β [49], 11β [50], 15β [49] and 15α [51]. A similar transformation to 6β,11α-dihydroxy-16α,17α-epoxyprogesterone was described for Aspergillus ochraceus ATCC 1008 [52].…”
Section: Discussionmentioning
confidence: 99%
“…Its 11α hydroxylation is a key step in synthesising prednisone and prednisolone or dexamethasone, and Rhizopus nigricans is the most widely used microorganism for industry purposes [48]. Other possible hydroxylation positions of this compound are 8β [49], 11β [50], 15β [49] and 15α [51]. A similar transformation to 6β,11α-dihydroxy-16α,17α-epoxyprogesterone was described for Aspergillus ochraceus ATCC 1008 [52].…”
Section: Discussionmentioning
confidence: 99%
“…Incubation of 1 resulted in the isolation of 14. Wu et al [80] concluded that the different hydroxylation sites between 11 and 12 suggested that the hydroxyl group or carbonyl group on the substrate at C-17 had influence on the location of introduced hydroxyl groups (Figure 15).…”
Section: Microbiological Transformations Of Steroidsmentioning
confidence: 99%
“…From the biotransformation of 203 using Corynespora cassiicola, 9α-hydroxycanrenone Biotransformation of Steroids Using Different Microorganisms DOI: http://dx.doi.org /10.5772/intechopen.85849 (208, 30%) was obtained, [96]. Conversion of canrenone (203) by Colletotrichum lini ST-1 gave two hydroxyl compounds, 15α-hydroxy-canrenone (209, 22%) and 11α,15α-dihydroxy-canrenone (210, 47%) ( Figure 27) [80].…”
Section: Microbiological Transformations Of Steroidsmentioning
confidence: 99%