Efficient Synthesis of Sulfonyl Diphenylsulfides Catalyzed via Cu–MOF of PCN‐6’

Liu, Na; Tian, Anqi; Ren, Zhi‐Lin; Wang, Long

doi:10.1002/slct.201902713

Cited by 14 publications

(6 citation statements)

References 65 publications

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“…1a). The previous study on PCN-6-M formation reported microparticles with irregular morphology 9,10 . A closer inspection of the MOF surface at high resolution showed an irregular net-like…”

Section: Resultsmentioning

confidence: 95%

“…PCN-6 has been studied for CO 2 capture as well, showing an uptake capacity of 4.3 mmol g −1 at 298 K and 1 bar 9 . Besides gas adsorption, owing to the presence of uncoordinated Cu sites, the non-catenated PCN-6’ form has found application in catalysis 10 . So far, PCN-6 has not been studied for the adsorptive capture of toxic acidic gases like H 2 S, which is the focus of this work.…”

Section: Introductionmentioning

confidence: 99%

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Probing the origin and stability of bivalency in copper based porous coordination network and its application for H2S gas capture

Gupta

Kim

Bae

et al. 2022

Sci Rep

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A bivalent Cu(I,II) metal–organic framework (MOF) based on the 4,4′,4″-s-Triazine-2,4,6-triyl-tribenzoate linker was synthesized via a solvothermal method. The MOF possessed 43.8% of the Cu sites as Cu+ with a surface area of 1257 m2 g−1. The detailed spectroscopic analysis confirmed dimethylformamide (DMF) solvent as the reductant responsible for Cu+ sites in the synthesized MOF. The Cu+ sites were easily accessible and prone to oxidation in hot water or acidic gas environment. The MOF showed water-induced structural change, which could be partially recovered after soaking in DMF solvent. The synthesized MOF showed a high hydrogen sulfide (H2S) uptake capacity of 4.3 mmol g–1 at 298 K and an extremely low H2S pressure of 0.0005 bar. The adsorption capacity was the highest among Cu-based MOFs with PCN-6-M being regenerable, which made it useful for deep desulfurization applications. The adsorbed H2S was mineralized to sulfide, sulfur, and sulfates, mediated by the Cu+/Cu2+ redox cycle in the presence of adsorbed water and molecular oxygen. Thus, the study confirmed that DMF as a reductant is responsible for the origin of bivalency in PCN-6-M and possibly in other Cu-based MOFs reported in the literature. Also, the developed MOF could be a potential candidate for flue gas desulfurization and gas purification applications.

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Section: Resultsmentioning

confidence: 95%

Section: Introductionmentioning

confidence: 99%

Probing the origin and stability of bivalency in copper based porous coordination network and its application for H2S gas capture

Gupta

Kim

Bae

et al. 2022

Sci Rep

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“…Sulfonyl diphenylsulfide derivatives 4 were obtained when the MOF as catalyst was eliminated, and the hydroxylation product 10 was captured by sulfonyl chloride 3 during in-situ preparation. [106]…”

Section: Cà S Cross-coupling Reactionsmentioning

confidence: 99%

“…Because of their unique chemical activity, sulfonyl diphenylsulfide derivatives play a significant role in the fields of synthetic medicine, insecticides, and dyes (Scheme 24). [106] T. A. To and co-workers synthesized the copper composed MOF Cu 2 (OBA) 2 (BPY) (XVII) and employed it as a practicable heterogeneous catalyst for the direct formation of CÀ S type bond to produce b-sulfonylvinylamines (64) from sodium sulfinates (62) and oxime acetates (61).…”

Section: Cà S Cross-coupling Reactionsmentioning

confidence: 99%

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An Exploration on Copper‐Based Metal‐Organic Frameworks as Propitious Heterogeneous Catalyst for Coupling Reactions

et al. 2023

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Metal‐organic frameworks (MOFs) have been considered as adaptable alternatives of interest in catalytic reactions. Modern MOFs research and advancements strongly support their employment as catalysts to produce significant organic molecules. Concerning how such substances might be utilized in heterogeneous catalysis, the entire potency of MOFs in value‐added organic transformations must be thoroughly investigated. Standard MOFs components including encapsulation materials, linkers, metal‐nodes, and coated structures frequently provide effective catalytic active sites that provide ways to lessen human efforts to implement novel natural reactions. The significant aspects of using MOFs as recyclable catalysts are their convenient fabrication, consistent porosity, substantial pore volume, reusability and durable framework in addition to cost‐effectiveness. Since MOFs were extensively explored, they may have been used to fabricate medicinal active compounds through coupling and organic transformations. In this review, several Cu‐based MOFs are examined along with their catalytic attributes that assist with the selective fabrication of the product organic moieties via various cross‐coupling reactions.

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