Electrical and mechanical properties of polyethylene/MWCNT composites produced by polymerization using Cp2ZrCl2 supported on MWCNTs

Abstract

Pristine multiwalled carbon nanotube (MWCNT)/polyethylene (PE) composites produced by in situ polymerization using a metallocene (Cp 2 ZrCl 2 ) immobilized onto MWCNT are used for measurement of electrical, thermo-and dynamic mechanical properties. As the content of MWCNT in the composites increased, electrical resistivity decreased and heat distortion temperature (HDT) and storage modulus increased due to well-dispersed CNT strands in the PE matrix. The lowest average electrical surface and volume resistivities were 1.0×10 10 Ω and 4.1×10 9 Ω·cm, respectively and this result was supported by electrostatic force microscopy (EFM). In practical point of view, decrease of electrical resistivity of the composites is highly important in fabrication of antistatic polyolefin products including PEs in this study.

The morphology evolution of polyethylene produced in the presence of a Ziegler‐type catalyst anchored on the surface of multi‐walled carbon nanotubes

“…It is well known that polyolefins have low electrical conductivity, which can lead to the accumulation of static charge during the operation of plastics. CNTs 28–33 introduced into the polymer matrix induce conductivity and decrease the static charge. The electrical conductivity of the composite depends on the content of CNTs, the structural characteristics of CNTs, and the uniformity of its distribution in the polymer matrix.…”