Electrical Conductivity of Molten Charge‐Asymmetric Salts: , , and Systems

Abstract

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Electrical Conductivity of Melts Containing Rare-Earth Halides. II. MCl-PrCl3 (M=Li, Rb, Cs)

“…As was found in [1] the data of [15] on the conductivity of fused individual NdCl 3 and fused systems NaCl-NdCl 3 and KCl-NdCl 3 are in good agree- NaCl [7] KCl [7] RbCl CsCl (our data) ment with our results on the MCl-NdCl 3 (M = alkaline metals) systems. Close coincidence of the fused PrCl 3 conductivity, received by the authors of the present work and in work of the same group [7], is the evidence of the adequate preparation of anhydrous PrCl 3 and the consequent reliability of other data on the conductivity of the fused NaCl-PrCl 3 and KClPrCl 3 systems [7].…”

“…sults are juxtaposed in Figure 1, and a noticeable difference among these data is observed. Our experimental data (see Table 1 and Figure 1) agree well with those, which appear to be the most reliable [3,4,7,8,11].…”

“…The maximum departure of our values from [3,8,11], which practically coincide, is +1.0%; from [7] +4.5%.…”

“…Kulagin, 1987 [8,11] Our data 330 points Dworkin, Iwadate, 1986 1969 [4] Pobirchenko, 1988 [9] Samylina, 1999 [13] [3] [7] [5] rides can be a part of the initial praseodymium chloride or may be formed during the experiments as the result of the interaction with atmosphere or constructional materials.…”

“…The specific conductivity dependence on the composition at 1173 K is shown in Figure 2 for each system. The NaCl-PrCl 3 and KCl-PrCl 3 systems were investigated in [7], and the corresponding data are also plotted in Figure 2 for comparison.…”