Electrochemical and morphological characterization of poly[(R)-(−)-3-(l-pyrrolyl)propyl-N-(3,5-dinitrobenzoyl)-α-phenylglycinate] films deposited on ITO electrodes

Ribeiro, Adriana S.; Silva, Alisson Urbano da; Ribeiro, Laura; Silva, José Ginaldo da; Navarro, Marcelo; Tonholo, Josealdo

doi:10.1016/j.jelechem.2005.04.001

Cited by 12 publications

(4 citation statements)

References 32 publications

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“…However, the response peak for glucose of Pd NPs/SWCNT electrode (3 mC of charge deposition) was shifted to À0.15 V. It is due to the difference in electrode morphology that occurs during the growth of Pd nanoparticle layers. The similar result was reported in previous research [47]. The measured current of the Pd NPs/SWCNT electrode to 5 mM glucose was 129.9 mA (line b).…”

Section: à2supporting

confidence: 90%

Electrochemical Patterning of Palladium Nanoparticles on a Single‐Walled Carbon Nanotube Platform and Its Application to Glucose Detection

Pham

Bui

et al. 2011

Electroanalysis

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Arrays of palladium nanoparticles (Pd NPs) were fabricated on flexible single-walled carbon nanotube (SWCNT) films, and the fabricated Pd NPs/SWCNT films were employed as electrodes for electrochemical glucose detection. Palladium particles with an average diameter of 20-40 nm were distributed homogeneously on the SWCNT film. The Pd NPs/SWCNT electrode displayed a good detection limit of 3.4 mM and two linear ranges for glucose concentration. Sensitivities were 313.9 AE 4.8 mA mM À1 cm À2 and 155.2 AE 2.6 mA mM À1 cm À2 respectively. Moreover, the Pd NPs/SWCNT showed high selectivity for glucose in the presence of l-ascorbic acid as an interfering compound.

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Section: à2supporting

confidence: 90%

Electrochemical Patterning of Palladium Nanoparticles on a Single‐Walled Carbon Nanotube Platform and Its Application to Glucose Detection

Pham

Bui

et al. 2011

Electroanalysis

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“…Electropolymerization of thiophene-, , pyrrole-, and carbazole-based , monomers has been extensively studied due to the interesting properties of the resulting conducting polymer (CP) films, e.g., their electrochromic behavior. − Electrochemical oxidative coupling of carbazole was first described by Ambrose and Nelson . Applying oxidative potentials, cation radicals are initially generated.…”

Section: Resultsmentioning

confidence: 99%

“…The six carbazole-based monomers were purchased from commercial suppliers or synthesized by us (see the Supporting Information). In our experiments, monomers with two, three, and four carbazole substituents have been used: Electropolymerization of thiophene-, 20,21 pyrrole-, 22 and carbazole-based 23,24 monomers has been extensively studied due to the interesting properties of the resulting conducting polymer (CP) films, e.g., their electrochromic behavior. 25−27 Electrochemical oxidative coupling of carbazole was first described by Ambrose and Nelson.…”

Section: ■ Results and Discussionmentioning

confidence: 99%

Electrogenerated Thin Films of Microporous Polymer Networks with Remarkably Increased Electrochemical Response to Nitroaromatic Analytes

Palma-Cando

Scherf

2015

ACS Appl. Mater. Interfaces

100

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Thin films of microporous polymer networks (MPNs) have been generated by electrochemical polymerization of a series of multifunctional carbazole-based monomers. The microporous films show high Brunauer-Emmett-Teller (BET) surface areas up to 1300 m2 g(-1) as directly measured by krypton sorption experiments. A correlation between the number of polymerizable carbazole units of the monomer and the resulting surface area is observed. Electrochemical sensing experiments with 1,3,5-trinitrobenzene as prototypical nitroaromatic analyte demonstrate an up to 180 times increased current response of MPN-modified glassy carbon electrodes in relation to the nonmodified electrode. The phenomenon probably involves intermolecular interactions between the electron-poor nitroaromatic analytes and the electron-rich, high surface area microporous deposits, with the electrochemical reduction at the MPN-modified electrodes being an adsorption-controlled process for low scan rates. We expect a high application potential of such MPN-modified electrodes for boosting the sensitivity of electrochemical sensor devices.

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“…Therefore, the properties can be adjusted by modification of the monomer structure by attaching different functional groups, such as, electron-donating and/or electronwithdrawing, n-dopable, or fluorescent substituents [10][11][12][13]. For instance, the appendage of a nitro group on the monomer structure would make the resulting polymers amenable for use in sensors or electrochemical capacitors [14,15].…”

Section: Introductionmentioning

confidence: 99%

Synthesis and characterization of fluorescent nitrobenzoyl polythiophenes

Coelho

Nascimento

Ribeiro

et al. 2015

Electrochimica Acta

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Electrochemical and morphological characterization of poly[(R)-(−)-3-(l-pyrrolyl)propyl-N-(3,5-dinitrobenzoyl)-α-phenylglycinate] films deposited on ITO electrodes

Cited by 12 publications

References 32 publications

Electrochemical Patterning of Palladium Nanoparticles on a Single‐Walled Carbon Nanotube Platform and Its Application to Glucose Detection

Electrochemical Patterning of Palladium Nanoparticles on a Single‐Walled Carbon Nanotube Platform and Its Application to Glucose Detection

Electrogenerated Thin Films of Microporous Polymer Networks with Remarkably Increased Electrochemical Response to Nitroaromatic Analytes

Synthesis and characterization of fluorescent nitrobenzoyl polythiophenes

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