2006
DOI: 10.1007/s10800-005-9112-9
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Electrochemical behavior of anatase TiO2 in aqueous lithium hydroxide electrolyte

Abstract: The electrochemical behavior of titanium dioxide (TiO 2 ) in aqueous lithium hydroxide (LiOH) electrolyte has been investigated. Cyclic voltammetry shows that electroreduction results in the formation of a number of products. X-ray diffraction of the electroreduced TiO 2 shows that Li x TiO 2 , Ti 2 O 3 , Ti 2 O and TiO are formed. The formation of Li x TiO 2 is confirmed through X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) studies of the electroreduced TiO 2 . The … Show more

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Cited by 50 publications
(32 citation statements)
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“…In 1994, Dahn et al [ 50 ] used aqueous electrolyte for Li-ion batteries. Following this paper, aqueous electrolytes were used in many other batteries [ 16 , 17 , 18 , 19 , 20 , 33 , 43 , 51 , 52 , 53 , 54 , 55 , 56 , 57 , 58 , 59 , 60 , 61 , 62 , 63 , 64 , 65 , 66 , 67 , 68 , 69 , 70 , 71 , 72 , 73 , 74 , 75 , 76 , 77 ]. In 2012, a rechargeable multivalent Al-ion battery with aqueous electrolyte was proposed as a promising candidate for high energy storage to compete with the Li-ion batteries [ 51 ].…”
Section: Overview On Multivalent Intercalation Batteriesmentioning
confidence: 99%
“…In 1994, Dahn et al [ 50 ] used aqueous electrolyte for Li-ion batteries. Following this paper, aqueous electrolytes were used in many other batteries [ 16 , 17 , 18 , 19 , 20 , 33 , 43 , 51 , 52 , 53 , 54 , 55 , 56 , 57 , 58 , 59 , 60 , 61 , 62 , 63 , 64 , 65 , 66 , 67 , 68 , 69 , 70 , 71 , 72 , 73 , 74 , 75 , 76 , 77 ]. In 2012, a rechargeable multivalent Al-ion battery with aqueous electrolyte was proposed as a promising candidate for high energy storage to compete with the Li-ion batteries [ 51 ].…”
Section: Overview On Multivalent Intercalation Batteriesmentioning
confidence: 99%
“…TiO 2 exists in different morphologies such as rutile, anatases, brookite, TiO 2 B (bronze), and TiO 2 R (ramsdellite). It is worth mentioning that the most chosen TiO 2 crystal phase for lithium ion batteries is the anatase structure due to its high capacity and lowcost production [100][101][102].…”
Section: Titanium Oxide (Tio 2 ) Nanofibersmentioning
confidence: 99%
“…Ti based dimensionally stable anodes (DSA), which have been broadly used in not only EW but also other industrial applications such as an active anode materials for Li-ion batteries, super capacitor, 18 titanium skeleton and organs for medical supplies, and chloride-alkaline industry owing to its high conductivity, low OEOP and good environment stability. [19][20][21][22] Various kinds of Ti based noble metallic oxide anodes, such as IrO 2 + ZrO 2 , IrO 2 + TiO 2 , RuO 2 + Ta 2 O 5 , IrO 2 + Ta 2 O 5 and IrO 2 + Nb 2 O 5 , have been reported to present long service life in acidic media and high electrocatalytic activity.…”
Section: Introductionmentioning
confidence: 99%