Electrochemical performance of CuNCN for sodium ion batteries and comparison with ZnNCN and lithium ion batteries

Synthesis and Characterisation of the Nitridocuprate(I) Nitride Carbodiimide (Sr6N)[CuN2][CN2]2

“…For M = Hg two modifications, one cyanamide and one carbodiimide, are known , . Interestingly, some of these compounds show potential applications as negative electrode materials for lithium and sodium ion batteries, corrosion protective layers, photovoltaic devices, fluorescent light sources, and light‐emitting diodes , . Due to the carbodiimide anion being a pseudo‐chalcogenide anion, it can act as a bridging ligand to allow effective magnetic super exchange between bridged paramagnetic cations, as seen for Cr 2 [CN 2 ] 3 and M [CN 2 ] ( M = Mn – Cu), which are isostructural to their respective oxide variants, exhibit similar magnetic ordering and also have the same colours .…”

“…For M = Hg two modifications, one cyanamide and one carbodiimide, are known. [13,14] Interestingly, some of these compounds show potential applications as negative electrode materials for lithium and sodium ion batteries, [15][16][17][18][19] corrosion protective layers, [20] photovoltaic devices, [21] fluorescent light sources [22,23] and light-emitting diodes. [24,25] Due to the carbodiimide anion being a pseudo-chalcogenide anion, it can act as a bridging ligand to allow effective magnetic super exchange between fraction and the identity of the [CN 2 ] 2anion as carbodiimide was confirmed by Raman spectroscopy.…”

Von Lithium‐ zu Natriumionenbatterien: Vorteile, Herausforderungen und Überraschendes

“…Hier kçnnen die Kapazitäten fürN atrium nämlich die fürL ithium über-treffen. [28] Tr otz der bestehenden Probleme stellen Konversionsreaktionen vom beschriebenen Ty pa uch weiterhin attraktive Forschungsziele dar,i nsbesondere in Anbetracht kostengünstiger Verbindungen wie Eisenoxide oder -sulfide. [29] 4.…”

Reversible High Capacity and Reaction Mechanism of Cr2(NCN)3 Negative Electrodes for Li‐Ion Batteries

“…In 2016, our group reported the excellent performance of FeNCN with, for example, an impressive rate capability up to 30 C and stable capacity for more than 100 cycles . This article was followed by other reports exploring the reaction mechanism of transition and main‐group metal carbodiimides versus Li and Na ions . Similarly to most transition‐metal based anode materials, these materials are expected to react electrochemically with lithium through a conversion reaction but the reaction pathways or mechanisms of these carbodiimides, especially the trivalent ones, are not yet completely clarified.…”

“…exploring the reaction mechanism of transition and main-group metal carbodiimides versus Li and Na ions. [28][29][30][31][32] Similarly to most transition-metal based anode materials, these materials are expected to react electrochemically with lithium through a conversion reaction but the reaction pathways or mechanisms of these carbodiimides, especially the trivalent ones, are not yet completely clarified.…”