1970
DOI: 10.1149/1.2407586
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Electrodeless Electrolysis

Abstract: Solid ionic conductors and fused salts were electrolyzed without contact of solid electrical leads. The current was carried to the materials to be electrolyzed either by means of electrons emitted by a hot filament or by a glow discharge. The materials were made the separating wall between the anode and cathode compartments of an apparatus constructed of glass or fused silica. Electrolysis of glass produced a white opaque material which did not seem to differ chemically from the original glass. Dendrites of se… Show more

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Cited by 9 publications
(7 citation statements)
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“…In a vacuum system, dendrites of several metals have been obtained in 1970 by a glow discharge electrolysis of molten metal salts [50]. C60 has been formed by electric discharges in liquid toluene [51] in 1993.…”
Section: Introductionmentioning
confidence: 99%
See 1 more Smart Citation
“…In a vacuum system, dendrites of several metals have been obtained in 1970 by a glow discharge electrolysis of molten metal salts [50]. C60 has been formed by electric discharges in liquid toluene [51] in 1993.…”
Section: Introductionmentioning
confidence: 99%
“…Since the plasma can provide electrons and radicals, and the metal ions can dissolve in the liquids, this unique plasma-liquid system is strongly attracted to the NM syntheses, and they fertilize and active a rapidly rising field of the PLI-based NM syntheses [42][43][44][45][46][47][48][49] in recent decades due to the strong requirement of large-scale syntheses of NMs and the fast development of various plasma sources. In a vacuum system, dendrites of several metals have been obtained in 1970 by a glow discharge electrolysis of molten metal salts [50]. C60 has been formed by electric discharges in liquid toluene [51] in 1993.…”
Section: Introductionmentioning
confidence: 99%
“…Moreover, in case of low pressure plasmas, nanomaterial synthesis is not limited to a small sized plasma region, which typically enhances the yield of produced nanomaterials. Using ionic liquids, Brenner et al [13] could obtain dendrites of several metals in a vacuum glow discharge system. Additionally, in 1998, Kawamura et al [88] synthesized micro-scaled fine Ag particles in an atmospheric pressure DC plasma system.…”
Section: Applications Of Plasma-liquid Systemsmentioning
confidence: 99%
“…After Gubkin, much attention was given to this new research field for the development of the GDE technique and for investigation of micro, spark, or arc discharges in liquid electrolytes [6,7,8,9]. Some groups, mainly Klemenc et al and Brenner et al [10,11,12,13], reproduced and improved Gubkin’s simple experiment in the 1950s and 1960s. Also, some studies followed on material synthesis from plasma-liquid interactions (PLIs) [14,15,16,17,18,19].…”
Section: Introductionmentioning
confidence: 99%
“…Brenner and Sligh reported the utilization of low-pressure glow discharge to prepare dendritic metals by cathode discharge electrolysis of molten salts. 20 However, because of the subatmospheric operation pressure, the charge transfer at the plasma−liquid interface has been neither clearly studied nor widely applied in electrolysis. Ito and co-workers have applied a kind of atmospheric-pressure arc discharge for the plasma-induced cathodic discharge electrolysis and successfully prepared a series of metal and alloy nanoparticles in molten salt.…”
mentioning
confidence: 99%