Electrodeposition of self-supported Ni-Mo-P film on Ni foam as an affordable and high-performance electrocatalyst toward hydrogen evolution reaction

Toghraei, A.; Shahrabi, T.; Darband, Gh. Barati

doi:10.1016/j.electacta.2020.135643

Cited by 112 publications

(42 citation statements)

References 58 publications

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“…Toghraei et al fabricated self-supported Ni-Mo-P coating on 3D Ni foam substrate (Ni-Mo-P/NF) by single-step galvanostatic electrodeposition method and studied the HER activity of this electrode in 1 m KOH electrolyte. [14] They have implemented the three-electrode electrodeposition configuration with a SCE as the reference electrode, a platinum as a counter electrode, and Ni foam as the working electrodes (Figure 5). The Ni foam acted as a substrate, and the electrodeposition was carried out under various concentrations of dissolved MoO 4 -2 and at different applied current densities.…”

Section: Galvanostatic Electrodeposition Methodsmentioning

confidence: 99%

See 1 more Smart Citation

Electrocatalysts by Electrodeposition: Recent Advances, Synthesis Methods, and Applications in Energy Conversion

Kale

Borse

Mohamed

et al. 2021

Adv Funct Materials

128

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The conventional environment polluting energy sources and the continuous growing energy demand compelled researchers to find alternative energy sources. Therefore, in recent years, extensive research has been carried out in synthesizing catalysts for energy conversion applications. This review focuses on the application of various electrodeposition methods in the synthesis of energy-related electrocatalyst and briefly discusses different electrocatalyst characterization techniques. Further, the influence of various parameters on the electrocatalyst activity and stability is highlighted. Electrocatalyst application in clean energy conversion reactions, such as the hydrogen evolution reaction, oxygen evolution reaction, oxygen reduction reaction, carbon dioxide reduction reaction, nitrogen reduction reaction along with the metalair/CO 2 battery, are reviewed. Finally, the comparative experimental data are provided as a reference to synthesize the next-generation electrodeposited electrocatalyst in clean energy conversions and beyond.

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Section: Galvanostatic Electrodeposition Methodsmentioning

confidence: 99%

mentioning

confidence: 99%

Electrocatalysts by Electrodeposition: Recent Advances, Synthesis Methods, and Applications in Energy Conversion

Kale

Borse

Mohamed

et al. 2021

Adv Funct Materials

128

View full text Add to dashboard Cite

show abstract

“…Iron [51], nickel [56] and nickel-molybdenum [57] phosphide nanostructures have been deposited from aqueous (sodium hypophosphite) baths [51,57] and deep-eutectic solvents (DES) [56] by continuous PS [51,56], GS [57] and CV [56] procedures. The resulting morphologies are more dependent on the substrate than on the electrolyte and the potentialcurrent-time program: continuous potentiostatic deposition on carbon fiber yields FeP nanocubes [51], whereas nanocrystalline films on Ni and Cu substrates [56,57] can be obtained by potentiostatic, galvanostatic or cyclic voltammetry methods. In addition, cobalt [55], nickelcobalt [53], or molybdenum-nickel [54] sulfides have also been deposited on nickel surfaces.…”

Section: Electrodeposition For Water Splitting Applicationsmentioning

confidence: 99%

“…Yet, due to the complexity of chemistries and morphologies sought after, it is evident that only the tip of the iceberg has been explored in the electrodeposition parameter space. In most cases, the chemical composition cannot be decoupled from the catalyst morphology [4,30,[35][36][37][38][39]48,56,57,78,79]. In general, the influence of only one parameter (concentration, potential, etc.)…”

Section: Analysis Of Innovative Electrodeposition Strategies and Conclusionmentioning

confidence: 99%

Electrodeposition of nanostructured catalysts for electrochemical energy conversion: Current trends and innovative strategies

López

Ustarroz

2021

Current Opinion in Electrochemistry

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This review discusses the latest advances in electrodeposition of nanostructured catalysts for electrochemical energy conversion: fuel cells, water splitting and carbon dioxide electroreduction. The method excels at preparing efficient and durable nanostructured materials, such as nanoparticles, single atom clusters, hierarchical bifunctional combinations of hydroxides, selenides, phosphides, etc. Yet, in most cases, chemical composition cannot be decoupled from catalyst morphology. This compromises the rational design of electrodeposition procedures since performance indicators depend on both morphology and surface chemistry. We expect electrodeposition will keep unraveling its potential as the preferred method for electrocatalyst synthesis once a deeper understanding of the electrochemical growth process is combined with complex chemistries to have control of the morphology and the surface composition of complex (bifunctional) electrocatalysts.

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“…[25] According to this theory, the catalysts combining Ni with other transition metals can be designed. [26] Among many candidate materials, NiMo-based catalysts are widely used in the study of HER [27][28][29][30] and OER, [31,32] showing excellent performance. Kotaro et al composited the NiMoN nanosheets supporting on carbon with 75 mV overpotential (10 mA cm À 2 ) for HER [33] and the NiMoO 4 synthesized by Chen et al through hydrothermal method showed excellent OER performance under alkaline environment afforded 10 mA cm À 2 at 340 mV.…”

Section: Introductionmentioning

confidence: 99%

Efficient Self‐Supported Bifunctional NiMo Alloy Electrocatalysts for Water Splitting in Alkaline Environment

Wang

Bai

et al. 2022

ChemistrySelect

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Hydrogen attracts researchers' attention because its combustion products are very clean and will not pollute the environment. Electrocatalytic water splitting is a sustainable hydrogen energy production technology, which splits water into hydrogen and oxygen. In electrocatalytic water splitting, high activity catalysts can reduce the potential barrier of catalytic reaction and speed up the reaction, among which transition metal alloy catalysts have attracted extensive attention in the application of electrocatalysis due to their excellent electrochemical activity, stability and easy preparation. In this paper, the NiMoO 4 precursor was firstly synthesized by the facile hydrothermal reaction, and then the self-supported NiMo alloy was synthesized by annealing. The results indicate that NiMo alloy has efficient hydrogen evolution activity (34 mV) and oxygen evolution activity (279 mV) at 10 mA cm À 2 . More importantly, the water splitting system consisting of NiMo alloys demonstrates excellent performance and stability. At 10 mA cm À 2 , the voltage is 1.489 V, and it can be stable for at least 10 hours at 70 mA cm À 2 . This study can provide some ideas for the study of water splitting electrocatalysts.

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Electrodeposition of self-supported Ni-Mo-P film on Ni foam as an affordable and high-performance electrocatalyst toward hydrogen evolution reaction

Cited by 112 publications

References 58 publications

Electrocatalysts by Electrodeposition: Recent Advances, Synthesis Methods, and Applications in Energy Conversion

Electrocatalysts by Electrodeposition: Recent Advances, Synthesis Methods, and Applications in Energy Conversion

Electrodeposition of nanostructured catalysts for electrochemical energy conversion: Current trends and innovative strategies

Efficient Self‐Supported Bifunctional NiMo Alloy Electrocatalysts for Water Splitting in Alkaline Environment

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