“…Recently, organic-intercalated layered solids have been studied in different elds as their new physical and chemical properties are dramatically different from their bulk counterparts such as their electrical properties, 1 mechanical properties, 2 thermal behavior, 3 surface and interfacial properties, 4 and so on. Surfactants are well known for their amphipathic organic molecular structure, which can be used to modify the surface properties of hydrophilic materials, such as layered double hydroxides, 5 layered metal phosphate 6 and two-dimensional layered materials, 4 to mix with the hydrophobic polymer chains to obtain wonderful nanocomposites. Their thermodynamics have signicant practical and theoretical interest, as a result of their congurational complexity, which can be impacted by their concentration, chain length or chemical environment.…”