The effect of microwave radiation at room temperature on the characteristics of Ta 2 O 5 (7-25 nm)-based capacitors with various gates (Al, W, TiN) has been investigated. The variation of the parameters upon treatment is a function of the initial properties of the devices. The permittivity of the stacks slightly increases, and both oxide charges and interface states density decrease after ∼5-10 s of irradiation. The parameter, however, that is definitely sensitive to the exposure is the leakage current-a current reduction, up to ∼2 orders of magnitude-and an improvement of the breakdown fields has been found for irradiated samples. The process is not accompanied either by additional oxidation of Si or by crystallization effects in the films. The current improvement is addressed to the annealing of gate-deposition-induced defects and defects due to reactions at the gate/Ta 2 O 5 interface rather than to annealing of poor-oxidation-related defects. The radiation-induced change of the mechanisms governing the conductivity in the stacks is discussed in terms of partial annealing of pre-existing electron traps. An Auger electron spectroscopy detectable variation in the composition of the films has not been observed within exposure times for which a change of the electrical characteristics has been established. Considering that the combination of metal gates with high-k layers is the solution for the further scaling of top-down microelectronic devices, short-time microwave radiation appears to be a promising way for leakage current reduction in Ta 2 O 5 stacks with metal gates, to a level adequate for the storage capacitor application.