In recent years, all-inorganic metal lead halide cesium perovskites (CsPbX 3 , X = Cl, Br, and I) have shown excellent luminescence performance in the field of wide color gamut backlight displays. However, Pb 2+ in CsPbX 3 easily leaks because of the unstable structure of CsPbX 3 , which seriously threatens human health. However, Mn-based metal halides (MHs) have unique environmentally friendly characteristics. In this work, Zn 2+ -doped Cs 3 MnBr 5 MHs were successfully prepared, which exhibited highly efficient green emissions at 520−522 nm. Moreover, Cs 3 Mn x Zn (1−x) Br 5 shows excellent stability at room temperature (25 °C) compared with Cs 3 MnBr 5 . More excitingly, when Cs 3 Mn x Zn (1−x) Br 5 was encapsulated in a polystyrene (PS) polymer, Cs 3 Mn x Zn (1−x) Br 5 @PS showed better water, acid, daylight, and blue light stabilities. In addition, the backlight display device was designed based on different green−red ratios and thicknesses of Cs 3 Mn x Zn (1−x) Br 5 @K 2 SiF 6 :Mn 4+ @PS light conversion films, and the color gamut was over 109% of the NTSC 1953 standard, which is better than that of the reported WLED devices based on Mn-based MHs thus far. This work undoubtedly shows that Mn-based MHs have great application potential in wide color gamut backlight displays and provide a practicable route to fabricate nontoxic, low-cost, and high-performance liquid crystal displays. KEYWORDS: Cs 3 Mn x Zn (1−x) Br 5 , PS, stability, color gamut, backlight display